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. Author manuscript; available in PMC: 2024 Dec 5.
Published in final edited form as: J Am Chem Soc. 2020 Oct 28;142(45):19239–19248. doi: 10.1021/jacs.0c09157

Table 3.

GC Results of the Ni-Catalyzed Oxidationa of Cyclohexane under N2 and Air

graphic file with name nihms-2037101-t0015.jpg
entry N2/air treatment with PPh3 A/K b
1 N2 yes 4.6 ± 0.1
2 no 4.5 ± 0.0
3 air yes 6.1 ± 0.8
4 no 4.2 ± 0.7
a

Conditions: 0.125 mmol mCPBA, 7.5 equiv 2, 0.1 mol % 1a, DCM/MeCN (3:1, 0.125 M), 50 °C, 5 min.

b

Arithmetic mean of three repeated experiments.