. 2024 Nov 19;4(6):705–711. doi: 10.1021/acsorginorgau.4c00071

Table 2. Hydrogenation of Amides to Amines Catalyzed by Rh₄Mo₄(Cp^E)/Al₂O₃.

Reaction conditions: 1 (0.1 mmol), H₂ (0.8 MPa), n-octane (0.5 mL), catalyst (10 mg, Rh: 1 wt %, 0.97 mol %), molecular sieves (3A, 20 mg), and 6 h.

1 (0.025 mmol), H₂ (0.8 MPa), n-octane (2 mL), catalyst (4 mg, Rh: 5 wt %, 7.8 mol %), molecular sieves (3A, 20 mg), and 10 h.

Table 2. Hydrogenation of Amides to Amines Catalyzed by Rh4Mo4(CpE)/Al2O3.