Table 2. Analysis Results of Trace and Rare Earth Elements in Sandstone of the Shawan Formationa.
samples | grayish-green zone |
black
oil zone |
light
gray uranium mineralized zone |
light
brown zone |
||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
YC3 | YC23 | YC5 | YC6 | YC9 | YC10 | YC12 | YC13 | YC15 | YC16 | YC17 | YC19 | YC27 | YC32 | |
Li | 9.88 | 88.74 | 3.23 | 4.57 | 38.42 | 6.37 | 6.14 | 5.09 | 10.24 | 7.22 | 16.78 | 7.31 | 40.64 | 27.14 |
Be | 2.82 | 2.92 | 1.37 | 1.20 | 2.50 | 1.85 | 1.54 | 1.54 | 1.28 | 1.86 | 1.37 | 2.39 | 1.97 | 1.84 |
Sc | 3.23 | 19.12 | 0.60 | 0.77 | 20.12 | 1.78 | 1.59 | 1.55 | 3.16 | 1.80 | 4.03 | 1.65 | 13.90 | 11.14 |
V | 16.99 | 121.20 | 4.97 | 6.07 | 133.20 | 15.96 | 10.18 | 12.71 | 19.18 | 13.26 | 21.42 | 9.86 | 97.14 | 80.22 |
Cr | 9.41 | 97.23 | 4.96 | 4.50 | 78.31 | 16.08 | 6.17 | 7.67 | 14.60 | 10.19 | 36.77 | 32.77 | 64.79 | 83.46 |
Mn | 306.1 | 657.1 | 55.95 | 48.47 | 601.9 | 1064.1 | 197.3 | 163.3 | 189.2 | 190.1 | 259.7 | 72.3 | 1139.9 | 691.9 |
Co | 1.41 | 20.46 | 0.46 | 0.52 | 37.98 | 1.15 | 2.82 | 1.04 | 2.26 | 0.38 | 1.50 | 0.75 | 11.80 | 8.40 |
Ni | 6.20 | 50.82 | 1.88 | 2.17 | 95.45 | 4.91 | 2.7 | 2.32 | 7.14 | 1.29 | 7.87 | 13.45 | 37.56 | 40.16 |
Cu | 3.17 | 38.39 | 1.40 | 1.44 | 52.29 | 2.68 | 4.63 | 1.52 | 3.53 | 2.82 | 3.72 | 3.25 | 32.81 | 25.31 |
Zn | 11.06 | 120.7 | 8.03 | 9.09 | 147.20 | 9.29 | 9.30 | 6.35 | 8.70 | 6.15 | 13.65 | 6.61 | 79.83 | 60.74 |
Ga | 5.22 | 22.46 | 5.20 | 4.64 | 26.55 | 6.60 | 5.07 | 4.21 | 5.72 | 3.62 | 6.50 | 3.76 | 15.87 | 14.86 |
Rb | 51.44 | 151.9 | 70.84 | 65.78 | 95.79 | 51.16 | 49.79 | 48.41 | 48.19 | 46.29 | 59.70 | 45.23 | 89.30 | 77.83 |
Sr | 429.7 | 231.7 | 85.5 | 89.1 | 1469.6 | 474.9 | 274.9 | 166.8 | 296.9 | 183.6 | 304.1 | 278.8 | 238.6 | 241.9 |
Hf | 1.71 | 5.19 | 3.59 | 1.36 | 4.98 | 2.44 | 2.97 | 1.53 | 1.71 | 1.45 | 1.56 | 1.57 | 4.07 | 4.44 |
Ta | 0.56 | 1.26 | 0.10 | 0.13 | 0.85 | 0.19 | 0.19 | 0.10 | 0.31 | 0.13 | 0.38 | 0.13 | 0.71 | 0.52 |
W | 0.46 | 3.60 | 0.38 | 0.32 | 2.91 | 2.13 | 0.33 | 0.35 | 0.60 | 0.21 | 0.98 | 0.65 | 1.87 | 1.63 |
Tl | 0.27 | 0.86 | 0.36 | 0.36 | 0.68 | 0.21 | 0.27 | 0.26 | 0.27 | 0.25 | 0.31 | 0.23 | 0.48 | 0.38 |
Pb | 8.35 | 22.46 | 10.96 | 10.54 | 27.74 | 7.94 | 7.89 | 7.45 | 11.63 | 7.8 | 11.62 | 6.19 | 20.17 | 16.77 |
Th | 1.99 | 13.02 | 1.49 | 1.62 | 10.20 | 1.85 | 2.80 | 1.49 | 1.81 | 1.93 | 2.74 | 1.95 | 9.06 | 6.18 |
U | 22.91 | 8.03 | 0.61 | 0.66 | 177.7 | 1902.1 | 28.19 | 127.1 | 28.81 | 32.80 | 96.90 | 30.61 | 1.91 | 1.59 |
Zr | 58.80 | 164.75 | 129.2 | 46.92 | 164.2 | 107.13 | 103.1 | 48.83 | 56.45 | 47.43 | 51.80 | 54.20 | 126.1 | 148.8 |
Nb | 3.84 | 17.68 | 1.40 | 1.59 | 12.33 | 3.57 | 2.07 | 1.45 | 3.68 | 1.43 | 4.50 | 1.87 | 10.92 | 7.86 |
Mo | 1.35 | 3.05 | 0.35 | 0.23 | 461.8 | 3818.2 | 10.06 | 27.54 | 13.78 | 9.05 | 44.78 | 76.65 | 1.17 | 1.73 |
Sn | 0.88 | 4.28 | 0.38 | 0.39 | 3.21 | 7.61 | 0.51 | 0.72 | 0.97 | 0.65 | 1.39 | 0.85 | 2.59 | 1.96 |
Cs | 1.78 | 14.83 | 2.25 | 2.10 | 8.71 | 2.10 | 1.83 | 1.79 | 2.08 | 1.60 | 2.84 | 1.83 | 8.20 | 5.50 |
Ba | 303.7 | 393.8 | 268.5 | 274.7 | 486.4 | 403.3 | 197.8 | 193.2 | 204.2 | 201.6 | 195.2 | 200.4 | 510.6 | 653.7 |
La | 10.18 | 33.44 | 4.92 | 6.21 | 34.54 | 3.91 | 5.82 | 5.71 | 5.16 | 3.71 | 7.71 | 4.08 | 29.44 | 23.47 |
Ce | 19.42 | 62.25 | 10.18 | 12.49 | 66.98 | 7.73 | 11.29 | 12.06 | 9.00 | 6.36 | 16.52 | 6.24 | 47.71 | 39.50 |
Pr | 2.32 | 8.34 | 0.87 | 1.22 | 9.22 | 0.81 | 1.29 | 1.52 | 0.99 | 0.61 | 1.78 | 0.54 | 6.90 | 5.64 |
Nd | 9.53 | 31.39 | 3.81 | 5.10 | 36.04 | 3.59 | 5.51 | 7.65 | 4.36 | 2.80 | 7.37 | 2.47 | 26.16 | 22.10 |
Sm | 1.92 | 6.18 | 0.76 | 1.00 | 6.87 | 0.82 | 1.15 | 1.75 | 0.91 | 0.58 | 1.51 | 0.52 | 5.17 | 4.55 |
Eu | 0.48 | 1.20 | 0.23 | 0.29 | 1.33 | 0.18 | 0.26 | 0.48 | 0.25 | 0.15 | 0.38 | 0.13 | 1.10 | 1.05 |
Gd | 1.73 | 5.15 | 0.70 | 0.88 | 4.80 | 0.74 | 1.11 | 1.88 | 0.95 | 0.56 | 1.37 | 0.57 | 4.62 | 4.14 |
Tb | 0.29 | 0.93 | 0.11 | 0.13 | 0.82 | 0.14 | 0.19 | 0.32 | 0.16 | 0.08 | 0.23 | 0.09 | 0.81 | 0.73 |
Dy | 1.60 | 4.73 | 0.64 | 0.76 | 3.89 | 0.90 | 1.15 | 1.78 | 1.00 | 0.56 | 1.32 | 0.67 | 4.15 | 3.82 |
Ho | 0.35 | 1.05 | 0.14 | 0.16 | 0.82 | 0.20 | 0.28 | 0.39 | 0.24 | 0.13 | 0.31 | 0.16 | 0.93 | 0.86 |
Er | 0.96 | 2.84 | 0.40 | 0.45 | 2.20 | 0.61 | 0.82 | 1.05 | 0.71 | 0.39 | 0.88 | 0.49 | 2.49 | 2.33 |
Tm | 0.14 | 0.41 | 0.06 | 0.07 | 0.33 | 0.10 | 0.12 | 0.15 | 0.11 | 0.06 | 0.13 | 0.08 | 0.36 | 0.33 |
Yb | 0.93 | 2.73 | 0.41 | 0.47 | 2.27 | 0.71 | 0.86 | 1.04 | 0.73 | 0.44 | 0.89 | 0.55 | 2.37 | 2.22 |
Lu | 0.14 | 0.42 | 0.06 | 0.07 | 0.35 | 0.11 | 0.14 | 0.16 | 0.11 | 0.07 | 0.14 | 0.09 | 0.37 | 0.35 |
Y | 10.41 | 27.55 | 6.18 | 3.98 | 20.76 | 6.56 | 10.00 | 9.57 | 7.76 | 4.02 | 9.57 | 4.71 | 25.60 | 23.93 |
ΣREE | 50.0 | 161.1 | 23.28 | 29.29 | 170.4 | 20.54 | 29.96 | 35.93 | 24.66 | 16.51 | 40.54 | 16.68 | 132.5 | 111.1 |
LREE | 43.85 | 142.8 | 20.76 | 26.30 | 154.9 | 17.03 | 25.31 | 29.17 | 20.67 | 14.20 | 35.28 | 13.99 | 116.4 | 96.3 |
HREE | 6.15 | 18.25 | 2.52 | 2.99 | 15.48 | 3.5 | 4.66 | 6.76 | 4.00 | 2.30 | 5.27 | 2.70 | 16.08 | 14.76 |
LREE/HREE | 7.13 | 7.82 | 8.25 | 8.80 | 10.01 | 4.86 | 5.43 | 4.31 | 5.16 | 6.16 | 6.70 | 5.19 | 7.24 | 6.52 |
(La/Yb)N | 7.83 | 8.77 | 8.63 | 9.49 | 10.89 | 3.93 | 4.87 | 3.95 | 5.09 | 6.00 | 6.18 | 5.34 | 8.91 | 7.58 |
La/Sc | 3.15 | 1.74 | 8.22 | 8.02 | 1.71 | 2.20 | 3.66 | 3.67 | 1.63 | 2.06 | 1.91 | 2.4 | 2.1 | 2.10 |
La/Th | 5.12 | 2.56 | 3.30 | 3.82 | 3.38 | 2.10 | 2.08 | 3.84 | 2.84 | 1.92 | 2.81 | 2.09 | 3.24 | 3.79 |
Co/Th | 0.7 | 1.57 | 0.3 | 0.3 | 3.7 | 0.62 | 1.00 | 0.7 | 1.2 | 0.19 | 0.54 | 0.3 | 1.30 | 1.36 |
δU | 0.98 | 0.78 | 0.71 | 0.71 | 0.99 | 0.99 | 0.98 | 0.99 | 0.98 | 0.99 | 0.99 | 0.98 | 0.55 | 0.6 |
V/Cr | 1.80 | 1.24 | 1.0 | 1.35 | 1.70 | 0.99 | 1.64 | 1.65 | 1.31 | 1.30 | 0.58 | 0.3 | 1.49 | 0.9 |
Ni/Co | 4.40 | 2.48 | 4.12 | 4.14 | 2.51 | 4.25 | 0.9 | 2.22 | 3.16 | 3.41 | 5.25 | 17.9 | 3.1 | 1.68 |
Sr/Ba | 1.41 | 0.58 | 0.31 | 0.32 | 3.02 | 1.17 | 1.38 | 0.86 | 1.45 | 0.91 | 1.55 | 1.39 | 0.46 | 0.37 |
Sr/Cu | 135.6 | 6.03 | 61.14 | 61.85 | 28.10 | 177.1 | 59.35 | 109.7 | 84.0 | 65.15 | 81.64 | 85.87 | 7.27 | 9.55 |
N is standard for chondrite. LREE = La + Ce + Pr + Nd + Sm + Eu, HREE = Gd + Tb + Dy + Ho + Er + Tm + Yb + Lu. δU = U/(0.5*(Th/3 + U)).38