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. 2024 Nov 28;9(49):48681–48696. doi: 10.1021/acsomega.4c07825

Table 2. Analysis Results of Trace and Rare Earth Elements in Sandstone of the Shawan Formationa.

samples grayish-green zone
black oil zone
light gray uranium mineralized zone
light brown zone
  YC3 YC23 YC5 YC6 YC9 YC10 YC12 YC13 YC15 YC16 YC17 YC19 YC27 YC32
Li 9.88 88.74 3.23 4.57 38.42 6.37 6.14 5.09 10.24 7.22 16.78 7.31 40.64 27.14
Be 2.82 2.92 1.37 1.20 2.50 1.85 1.54 1.54 1.28 1.86 1.37 2.39 1.97 1.84
Sc 3.23 19.12 0.60 0.77 20.12 1.78 1.59 1.55 3.16 1.80 4.03 1.65 13.90 11.14
V 16.99 121.20 4.97 6.07 133.20 15.96 10.18 12.71 19.18 13.26 21.42 9.86 97.14 80.22
Cr 9.41 97.23 4.96 4.50 78.31 16.08 6.17 7.67 14.60 10.19 36.77 32.77 64.79 83.46
Mn 306.1 657.1 55.95 48.47 601.9 1064.1 197.3 163.3 189.2 190.1 259.7 72.3 1139.9 691.9
Co 1.41 20.46 0.46 0.52 37.98 1.15 2.82 1.04 2.26 0.38 1.50 0.75 11.80 8.40
Ni 6.20 50.82 1.88 2.17 95.45 4.91 2.7 2.32 7.14 1.29 7.87 13.45 37.56 40.16
Cu 3.17 38.39 1.40 1.44 52.29 2.68 4.63 1.52 3.53 2.82 3.72 3.25 32.81 25.31
Zn 11.06 120.7 8.03 9.09 147.20 9.29 9.30 6.35 8.70 6.15 13.65 6.61 79.83 60.74
Ga 5.22 22.46 5.20 4.64 26.55 6.60 5.07 4.21 5.72 3.62 6.50 3.76 15.87 14.86
Rb 51.44 151.9 70.84 65.78 95.79 51.16 49.79 48.41 48.19 46.29 59.70 45.23 89.30 77.83
Sr 429.7 231.7 85.5 89.1 1469.6 474.9 274.9 166.8 296.9 183.6 304.1 278.8 238.6 241.9
Hf 1.71 5.19 3.59 1.36 4.98 2.44 2.97 1.53 1.71 1.45 1.56 1.57 4.07 4.44
Ta 0.56 1.26 0.10 0.13 0.85 0.19 0.19 0.10 0.31 0.13 0.38 0.13 0.71 0.52
W 0.46 3.60 0.38 0.32 2.91 2.13 0.33 0.35 0.60 0.21 0.98 0.65 1.87 1.63
Tl 0.27 0.86 0.36 0.36 0.68 0.21 0.27 0.26 0.27 0.25 0.31 0.23 0.48 0.38
Pb 8.35 22.46 10.96 10.54 27.74 7.94 7.89 7.45 11.63 7.8 11.62 6.19 20.17 16.77
Th 1.99 13.02 1.49 1.62 10.20 1.85 2.80 1.49 1.81 1.93 2.74 1.95 9.06 6.18
U 22.91 8.03 0.61 0.66 177.7 1902.1 28.19 127.1 28.81 32.80 96.90 30.61 1.91 1.59
Zr 58.80 164.75 129.2 46.92 164.2 107.13 103.1 48.83 56.45 47.43 51.80 54.20 126.1 148.8
Nb 3.84 17.68 1.40 1.59 12.33 3.57 2.07 1.45 3.68 1.43 4.50 1.87 10.92 7.86
Mo 1.35 3.05 0.35 0.23 461.8 3818.2 10.06 27.54 13.78 9.05 44.78 76.65 1.17 1.73
Sn 0.88 4.28 0.38 0.39 3.21 7.61 0.51 0.72 0.97 0.65 1.39 0.85 2.59 1.96
Cs 1.78 14.83 2.25 2.10 8.71 2.10 1.83 1.79 2.08 1.60 2.84 1.83 8.20 5.50
Ba 303.7 393.8 268.5 274.7 486.4 403.3 197.8 193.2 204.2 201.6 195.2 200.4 510.6 653.7
La 10.18 33.44 4.92 6.21 34.54 3.91 5.82 5.71 5.16 3.71 7.71 4.08 29.44 23.47
Ce 19.42 62.25 10.18 12.49 66.98 7.73 11.29 12.06 9.00 6.36 16.52 6.24 47.71 39.50
Pr 2.32 8.34 0.87 1.22 9.22 0.81 1.29 1.52 0.99 0.61 1.78 0.54 6.90 5.64
Nd 9.53 31.39 3.81 5.10 36.04 3.59 5.51 7.65 4.36 2.80 7.37 2.47 26.16 22.10
Sm 1.92 6.18 0.76 1.00 6.87 0.82 1.15 1.75 0.91 0.58 1.51 0.52 5.17 4.55
Eu 0.48 1.20 0.23 0.29 1.33 0.18 0.26 0.48 0.25 0.15 0.38 0.13 1.10 1.05
Gd 1.73 5.15 0.70 0.88 4.80 0.74 1.11 1.88 0.95 0.56 1.37 0.57 4.62 4.14
Tb 0.29 0.93 0.11 0.13 0.82 0.14 0.19 0.32 0.16 0.08 0.23 0.09 0.81 0.73
Dy 1.60 4.73 0.64 0.76 3.89 0.90 1.15 1.78 1.00 0.56 1.32 0.67 4.15 3.82
Ho 0.35 1.05 0.14 0.16 0.82 0.20 0.28 0.39 0.24 0.13 0.31 0.16 0.93 0.86
Er 0.96 2.84 0.40 0.45 2.20 0.61 0.82 1.05 0.71 0.39 0.88 0.49 2.49 2.33
Tm 0.14 0.41 0.06 0.07 0.33 0.10 0.12 0.15 0.11 0.06 0.13 0.08 0.36 0.33
Yb 0.93 2.73 0.41 0.47 2.27 0.71 0.86 1.04 0.73 0.44 0.89 0.55 2.37 2.22
Lu 0.14 0.42 0.06 0.07 0.35 0.11 0.14 0.16 0.11 0.07 0.14 0.09 0.37 0.35
Y 10.41 27.55 6.18 3.98 20.76 6.56 10.00 9.57 7.76 4.02 9.57 4.71 25.60 23.93
ΣREE 50.0 161.1 23.28 29.29 170.4 20.54 29.96 35.93 24.66 16.51 40.54 16.68 132.5 111.1
LREE 43.85 142.8 20.76 26.30 154.9 17.03 25.31 29.17 20.67 14.20 35.28 13.99 116.4 96.3
HREE 6.15 18.25 2.52 2.99 15.48 3.5 4.66 6.76 4.00 2.30 5.27 2.70 16.08 14.76
LREE/HREE 7.13 7.82 8.25 8.80 10.01 4.86 5.43 4.31 5.16 6.16 6.70 5.19 7.24 6.52
(La/Yb)N 7.83 8.77 8.63 9.49 10.89 3.93 4.87 3.95 5.09 6.00 6.18 5.34 8.91 7.58
La/Sc 3.15 1.74 8.22 8.02 1.71 2.20 3.66 3.67 1.63 2.06 1.91 2.4 2.1 2.10
La/Th 5.12 2.56 3.30 3.82 3.38 2.10 2.08 3.84 2.84 1.92 2.81 2.09 3.24 3.79
Co/Th 0.7 1.57 0.3 0.3 3.7 0.62 1.00 0.7 1.2 0.19 0.54 0.3 1.30 1.36
δU 0.98 0.78 0.71 0.71 0.99 0.99 0.98 0.99 0.98 0.99 0.99 0.98 0.55 0.6
V/Cr 1.80 1.24 1.0 1.35 1.70 0.99 1.64 1.65 1.31 1.30 0.58 0.3 1.49 0.9
Ni/Co 4.40 2.48 4.12 4.14 2.51 4.25 0.9 2.22 3.16 3.41 5.25 17.9 3.1 1.68
Sr/Ba 1.41 0.58 0.31 0.32 3.02 1.17 1.38 0.86 1.45 0.91 1.55 1.39 0.46 0.37
Sr/Cu 135.6 6.03 61.14 61.85 28.10 177.1 59.35 109.7 84.0 65.15 81.64 85.87 7.27 9.55
a

N is standard for chondrite. LREE = La + Ce + Pr + Nd + Sm + Eu, HREE = Gd + Tb + Dy + Ho + Er + Tm + Yb + Lu. δU = U/(0.5*(Th/3 + U)).38