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. 2024 Oct 23;36(50):2410282. doi: 10.1002/adma.202410282

Figure 2.

Figure 2

a) Specific heat divided by temperature C p /T of EuAl12O19 as a function of temperature revealing a second order phase transition at T S = 49 K and the ferromagnetic transition at T C = 1.3 K. b) Dielectric permittivity of EuAl12O19 along the c axis measured at a frequency of f = 12 kHz as a function of temperature. The transition at T S =49 K is clearly indicated by an abrupt change of slope. The red curve is a Curie–Weiss fit giving the large negative Curie–Weiss temperature of T CW = −117 K. c) Pyroelectric current in black and polarization in red as a function of temperature. The crystal was initially cooled down to T = 2 K under an electric field of E DC = 3.2 kV cm−1 along the c axis. Then the pyroelectric current was measured upon heating at q = 1 K min−1 in absence of electric field. It shows a strong reduction of the polarization around T ≈ 4 K followed by its suppression around  T S= 49 K.