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. 2024 Nov 26;58(49):21589–21603. doi: 10.1021/acs.est.4c02116

Table 1. Main and Interaction Effects from Linear Models of Decay Parameters and Environmental Variablesa,b.

    labile OM (green tea)
recalcitrant OM (rooibos tea)
model explanatory variables A ka ks A ka ks
ecosystem & climate ecosystem:precipitation            
ecosystem:temperature 8.49***   8.57***      
ecosystem:temperature variation            
ecosystem 170.99*** 319.6*** 2404.6*** 273.15*** 449.65*** 5444.0***
precipitation            
temperature mean 18.45***   18.34*** 15.84***   37.34***
temperature variation 0.47   0.908      
days of incubation 2.64     7.21** 7.10** 12.48***
macroclimate macroclimate 6.51*** 3.21** 7.30*** 4.02*** 1.46 13.03***
days of incubation 3.30* 2.51 3.05* 5.25** 8.32*** 18.0***
freshwater wetland IUCN Typologies 2.0 4.91*** 0.48 5.06*** 2.45* 1.02 8.16***
days of incubation 0.291 2.26 1.31 3.01 2.42 0.77
a

Each model is run independently for the six OM type and decay parameter combinations. For the ecosystem and climate model, the starting model included all eight variables. We used the Bayesian information criterion (BIC) to identify the best-fitting model, for which we report F-values and significance for each variable. Missing F-values in the table indicate variables selected against by BIC model selection. The macroclimate categories are presented in Figure 1. The freshwater wetland model uses the IUCN Typologies 2.0 that incorporate climate, inundation, and vegetation characteristics. Temperature variation represents the mean monthly variation during the timeframe of incubation. Two decay equations were applied to site-level time series to provide information on different stages of decay. An asymptotic exponential model (eq 1) provides A (proportion of stable mass remaining) and ka (rate constant of early decay, i.e., leaching). A single exponential decay model (eq 2) provides ks values that represent the overall decay rate constant. Values represent F-values, and significant p-values are in bold. Precipitation is in mm units.

b

p-values: *** < 0.001, ** 0.001 ≤ to ≤ 0.01, * 0.01 < to ≤ 0.05.