Table 2. Summary of Device Parameters for Bulk-Heterojunction (BHJ) OSCs with and without PVDF-Based Ferroelectric Additives under AM 1.5G Irradiation at 100 mW cm–2a.
| Additive | Concentration | Jsc (mA cm–2) | Voc (V) | FF (%) | PCE (%) |
|---|---|---|---|---|---|
| As-castb | – | 11.84 ± 0.68 | 0.790 ± 0.005 | 45.3 ± 1.5 | 4.23 ± 0.44 (4.67) |
| NMP onlyb | 3.0 vol % | 19.13 ± 0.30 | 0.796 ± 0.003 | 65.4 ± 0.3 | 9.96 ± 0.24 (10.20) |
| P1b | 1.5 wt % | 19.83 ± 0.36 | 0.803 ± 0.001 | 61.5 ± 0.7 | 9.79 ± 0.31 (10.10) |
| P2b | 1.5 wt % | 20.01 ± 0.29 | 0.810 ± 0.002 | 66.1 ± 0.4 | 10.72 ± 0.30 (11.02) |
| P3b | 2.0 wt % | 19.75 ± 0.32 | 0.794 ± 0.001 | 65.0 ± 0.8 | 10.20 ± 0.30 (10.50) |
| P4b | 1.5 wt % | 19.78 ± 0.31 | 0.805 ± 0.002 | 66.4 ± 0.4 | 10.58 ± 0.25 (10.83) |
| As-castc | – | 17.01 ± 0.15 | 0.829 ± 0.004 | 62.1 ± 1.2 | 8.84 ± 0.20 (9.04) |
| P2c | 1.0 wt % | 18.94 ± 0.15 | 0.829 ± 0.002 | 73.9 ± 0.3 | 11.61 ± 0.15 (11.76) |
Ferroelectric additives are marked in bold. Data corresponds to the average value of 10 devices and deviation from its maximum; data in parentheses corresponds to the maximum values.
PTB7-Th:PC71BM based OSC devices.
PM6:IT-4F based OSC devices. Adapted with permission from ref (10). Copyright 2020 Elsevier.