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. 2024 Nov 25;124(23):13331–13369. doi: 10.1021/acs.chemrev.4c00490

Table 2. Summary of Device Parameters for Bulk-Heterojunction (BHJ) OSCs with and without PVDF-Based Ferroelectric Additives under AM 1.5G Irradiation at 100 mW cm–2a.

Additive Concentration Jsc (mA cm–2) Voc (V) FF (%) PCE (%)
As-castb 11.84 ± 0.68 0.790 ± 0.005 45.3 ± 1.5 4.23 ± 0.44 (4.67)
NMP onlyb 3.0 vol % 19.13 ± 0.30 0.796 ± 0.003 65.4 ± 0.3 9.96 ± 0.24 (10.20)
P1b 1.5 wt % 19.83 ± 0.36 0.803 ± 0.001 61.5 ± 0.7 9.79 ± 0.31 (10.10)
P2b 1.5 wt % 20.01 ± 0.29 0.810 ± 0.002 66.1 ± 0.4 10.72 ± 0.30 (11.02)
P3b 2.0 wt % 19.75 ± 0.32 0.794 ± 0.001 65.0 ± 0.8 10.20 ± 0.30 (10.50)
P4b 1.5 wt % 19.78 ± 0.31 0.805 ± 0.002 66.4 ± 0.4 10.58 ± 0.25 (10.83)
As-castc 17.01 ± 0.15 0.829 ± 0.004 62.1 ± 1.2 8.84 ± 0.20 (9.04)
P2c 1.0 wt % 18.94 ± 0.15 0.829 ± 0.002 73.9 ± 0.3 11.61 ± 0.15 (11.76)
a

Ferroelectric additives are marked in bold. Data corresponds to the average value of 10 devices and deviation from its maximum; data in parentheses corresponds to the maximum values.

b

PTB7-Th:PC71BM based OSC devices.

c

PM6:IT-4F based OSC devices. Adapted with permission from ref (10). Copyright 2020 Elsevier.