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. 2024 Nov 21;29(23):5510. doi: 10.3390/molecules29235510

Table 3.

Attribution of the HSQC’s signal of hydrolysed TSP. The observed monosaccharide is in bold, while the monosaccharide linked is in the parentheses. Glc-glucose; Xyl-xylose; Gal-galactose.

Monosaccharide Residues Chemical Shift (ppm)
H/C
1 2 3 4 5 6
GlcNR 4.55/105.2 3.33/75.7 3.51/78.2 3.51/72.1 3.69/77.0 3.77/68.5
Glc-(Xyl) 4.55/105.2 3.40/75.4 3.67/76.8 3.67/81.9 3.81/76.0 3.99–3.92/68.7
Glc-(Xyl-Gal) 4.55/105.2 3.40/75.4 3.67/76.8 3.67/82.6 3.89/76.1 3.95–3.91/69.4
Glcα 5.21/94.4 3.62/73.8 3.82/74.1 3.68/81.9 3.93/72.6 3.86/62.6
Glcβ 4.65/98.3 3.29/76.5 3.65/77.1 3.68/81.7 3.60/77.2 3.93–3.81/62.7
Xyl-(Gal) 5.16/101.4 3.66/82.7 3.90/74.6 3.71/72.1 3.71–3.56/63.9 -
Xyl-(Glc) 4.95/101.6 3.54/74.1 3.72/75.7 3.59/72.1 3.71–3.56/63.9 -
Xyl-(GlcNR) 4.93/100.9 3.54/74.1 3.72/75.7 3.63/72.1 3.71–3.56/63.9 -
Gal 4.55/107.2 3.60/73.8 3.65/75.1 3.91/71.3 3.67/77.7 3.77/63.7