. 2024 Dec 17. Online ahead of print. doi: 10.1039/d4sc07292h

Table 1. Crystal and textural properties of the H-S@MgAl-LDH and H-S@CZMA-LDHs after five successive iterations of calcination–reconstruction with a 15 mM CuZn-containing solution.

Sample	LDH lattice parameters^a [nm]		LDH d(003) [nm]	LDH crystallite size^b [nm]		S _BET [m² g⁻¹]	V _micro [cm³ g⁻¹]	V _meso [cm³ g⁻¹]	V _total [cm³ g⁻¹]
Sample	a	c	LDH d(003) [nm]	D ₍₀₀₃₎	D ₍₁₁₀₎	S _BET [m² g⁻¹]	V _micro [cm³ g⁻¹]	V _meso [cm³ g⁻¹]	V _total [cm³ g⁻¹]
H-S@MA-LDH	0.3049	2.308	0.769	7.9	17.9	224	0.008	0.66	0.89
H-S@CZMA-LDH_R1	0.3062	2.318	0.773	13.9	15.0	163	0.009	0.68	0.67
H-S@CZMA-LDH_R2	0.3061	2.318	0.773	9.8	9.2	157	0.012	0.70	0.66
H-S@CZMA-LDH_R3	0.3065	2.312	0.771	15.8	9.9	158	0.012	0.74	0.73
H-S@CZMA-LDH_R4	0.3067	2.306	0.769	14.8	10.9	158	0.010	0.75	0.74
H-S@CZMA-LDH_R5	0.3073	2.302	0.767	14.2	13.5	179	0.002	0.66	0.74

a = 2d₁₁₀, c = 3d₀₀₃.

Crystallite size of LDH in stacking or plane direction (D₍₀₀₃₎ and D₍₁₁₀₎, respectively), calculated according to Scherrer equation: D_(hkl) = 0.9 × λ/(β × cos θ), λ = 0.154 nm, θ is the position (deg.), and β is the FWHM (rad.) of the Bragg diffraction peaks.