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. 2024 Dec 5;12:1502840. doi: 10.3389/fchem.2024.1502840

FIGURE 2.

FIGURE 2

Relationships η=η(Ψ) (left diagram) and ϕ¯(Ψ) (right diagram) according to Equation 13. Curves of the same color refer to z=2 (red), z=4 (blue), and z=6 (green) and are calculated for ω=1/2 (solid colored lines), ω=1 (broken lines), and ω=1.5 (dotted lines). For ω=0 , Equation 13 predicts η=tanh(Ψ) irrespective of z (the black curve on the left diagram). All curves colored red (z=2) follow the explicit expressions in Equation 15. The thick transparent lines in the left diagram represent third-order approximations of η(Ψ) , as specified in Equations 29, 30. They will be utilized in Sections 3.1, 3.2 to calculate the differential capacitance for the linearized model and beyond that using a perturbation approach.