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. 2024 Sep 12. Online ahead of print. doi: 10.1039/d4sc02645d

Table 5. Effect of the alkenyl substituent and counteranion in a cationic enantioselective Ir(i)-catalyzed PKR.

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Entry R X Solvent Yield (%) ee (%)
1 H TfO DME 85 91
2 " BArF " 69 85
3 Me TfO " 9 58
4 " BArF " Trace
5 " TfO THF 10 71
6 " BArF " 28 64