Table 2. Fluorescence Lifetimes of 1 upon the Hydrostatic Pressurization in H2O at Room Temperaturea.
pressure (MPa) | τ1 (ns) | A1 | τ2 (ns) | A2 | χ2 |
---|---|---|---|---|---|
40 | 0.42 | 0.93 | 3.2 | 0.07 | 1.1 |
80 | 0.40 | 0.92 | 3.0 | 0.08 | 1.0 |
120 | 0.39 | 0.92 | 2.8 | 0.08 | 1.2 |
160 | 0.38 | 0.92 | 2.9 | 0.08 | 1.2 |
200 | 0.36 | 0.90 | 2.4 | 0.10 | 1.3 |
240 | 0.36 | 0.90 | 2.3 | 0.10 | 0.9 |
280 | 0.35 | 0.90 | 2.3 | 0.10 | 1.1 |
Fluorescence lifetime (τi) and relative abundance (Ai) of each excited species, determined by the single-photon counting method in nondegassed solution; [1] = 87.9 μM, λem 525 nm.