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. 2024 Oct 21;4(6):435–442. doi: 10.1021/acsnanoscienceau.4c00052

Table 2. Fluorescence Lifetimes of 1 upon the Hydrostatic Pressurization in H2O at Room Temperaturea.

pressure (MPa) τ1 (ns) A1 τ2 (ns) A2 χ2
40 0.42 0.93 3.2 0.07 1.1
80 0.40 0.92 3.0 0.08 1.0
120 0.39 0.92 2.8 0.08 1.2
160 0.38 0.92 2.9 0.08 1.2
200 0.36 0.90 2.4 0.10 1.3
240 0.36 0.90 2.3 0.10 0.9
280 0.35 0.90 2.3 0.10 1.1
a

Fluorescence lifetime (τi) and relative abundance (Ai) of each excited species, determined by the single-photon counting method in nondegassed solution; [1] = 87.9 μM, λem 525 nm.