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. 2024 Dec 10;146(50):34962–34969. doi: 10.1021/jacs.4c14642

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© 2024 The Authors. Published by American Chemical Society

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Stoichiometric cycle illustrating the synthesis of [Cu₂(μ-NO)(μ-OH)DPFN][NTf₂]₂ (4) and its deprotonation to yield [Cu₂(μ-κ¹:κ¹-O₂N)DPFN][NTf₂] (2) via a dicopper(II,II) μ-NO, μ-O intermediate that undergoes N–O bond formation. The DFT-calculated geometry of [Cu₂(μ-NO)(μ-O)DPFN]⁺ is also shown with hydrogens omitted for clarity. *Yield determined by integration of the ¹H NMR spectrum against an internal standard.