Table 1. Photochemical Products Characterized by GC-MS during the Hydrogen-Rich and Hydrogen-Poor Experimentsa.
compound | hydrogen-rich | hydrogen-poor | (6 h) | (24 h) |
---|---|---|---|---|
C2H2 | √ | √ | (+) | (+) |
C2H4 | √ | √ | (+) | (+) |
C2H6 | √ | √ | (−) | (+) |
C3H8 | √ | √ | (−) | (+) |
n-C4H10 | √ | √ | (−) | (+) |
iso-C4H10 | √ | √ | (−) | (+) |
n-C5H12 | √ | × | × | × |
iso-C5H12 | √ | × | × | × |
HCN | √ | × | × | × |
CH3CN | √ | √ | (−) | (−) |
For products detected in both experiments, (+) and (−) indicate if more or less of that product was detected in the hydrogen-poor experiments compared to that in the hydrogen-rich experiments at hour 6 and hour 24.