Scheme 2. Scope for C–C σ Bond Amination.

Isolated yield. The ee was determined by HPLC analysis.

Morpholine 2a (1.0 equiv) as the nucleophile was used.

[Pd(allyl)Cl]₂ (4 mol %), L11 (8.8 mol %), NaBAr^F₄ (8.8 mol %), and 2 (5 equiv) were used.

p-Xylene was used as the solvent.

Pd(allyl)Cl]₂ (4 mol %), L11 (8.8 mol %), and NaBAr^F₄ (8.8 mol %) were used.

Nucleophile (1.0 equiv), electrophile (2.0 equiv), and ligand L16 were used. See SI for more detailed conditions.

Cs₂CO₃ was used.

The reaction temperature was 0 °C.

2 (5 equiv) was used.