Table 2. Kinectic Parameter for 50% FA Conversion Using [RuCl₂(PNP)] as a Catalyst^abc.

Entry	Temp (°C)	Time (h)	TON	TOF (h–1)	kobs × 10–2 (min.–1)
1	60	0.81	590	728	6.85
2	70	0.77	590	766	11.05
3	75	0.35	590	1685	22.34
4	80	0.21	590	2809	39.47
5	90	0.10	590	5900	50.89
6	100	0.09	590	6555	70.83

^aSolvent = HMDSO (10 mL) containing THF (1 mL).

^bMolar ratio Ru/FA/NEt3 = 1/1204/843.

^c[Ru] loaded = 0.08% related to FA.