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. 2024 Dec 18;12:1502401. doi: 10.3389/fchem.2024.1502401

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Copyright © 2024 Hossain, Coe-Sessions, Ault, Gboyero, Wenzel, Dhokale, Davies, Yang, de Sousa Oliveira, Li and Hoberg.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

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“The two-step protocol for synthesizing MOF/polymer hybrids and their composites with fibers. (A) Reaction scheme. Step 1: Solvent-assisted ligand incorporation (SALI) of ACPA (initiator) into a Zr-MOF; step 2: free-radical polymerization in a MOF (FRaP-in-MOF) of acrylate monomers, (B) SALI of 6- (MOF-808) or 8-connected (NU-1000) Zr-nodes with ACPA followed by temperature-induced generation of carbon-centered radicals, (C) drop-casting of MOF/polymer hybrids on PP and AC fibers, (D) hydrolysis of a nerve agent simulant, diisopropyl fluorophosphate (DIFP), catalyzed by the MOF/polymer/fiber composite (conditions: RT, 24 h).” Reprinted with permission (Pander et al., 2023).