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. 2024 Dec 19;15:1498768. doi: 10.3389/fphar.2024.1498768

TABLE 1.

Metabolites extracted from Herpetospermum pedunculosum seeds.

No. Name Molecular formula Extract Separation method Identification method References
Lignan
1 Herpetriol C30H34O9 Ethyl alcohol — UV, IR,MS, 1H-NMR, 13C-NMR Kaouadji et al. (1979)
2 Herpetetrol C40H44O12 Ethyl alcohol — UV, MS, 1H-NMR, 13C-NMR Kaouadji et al. (1979)
3 Herpepentol C50H54O15 MeOH — MS, 1H-NMR, 13C-NMR Kaouadji and Pieraccini (1984a)
4 Herpetetradione C40H42O12 MeOH — MS, 1H-NMR, 13C-NMR Kaouadji and Favre-Bonvin (1984a)
5 Herpetetrone C40H42O13 MeOH Polyamide CC6 and sephadex LH-20, chromatography UV, IR, MS, 1H-NMR Kaouadji et al. (1987)
6 Herpetrione C30H32O10 Ethyl alcohol — MS, 1H-NMR, 13C-NMR Kaouadji and Jean (1983)
7 Herpetone C29H30O9 Ethyl alcohol Silica gel column chromatography, preparative HPLC MS, IR, 1H-NMR, 13C-NMR Zhang et al. (2006)
8 Herpetol C20H20O6 Ethyl alcohol — UV, MS, 1H-NMR, 13C-NMR Kaouadji and Pieraccini (1984a)
9 Dehydrodiconiferyl alcohol C20H22O6 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC UV, 1H-NMR, 13C-NMR Ma (2020)
10 Herpetosin B C20H22O7 Ethyl acetate Silica gel column chromatography UV, IR, MS, 13C-NMR, 1H-NMR Xu (2012)
11 Herpetal C20H18O6 Ethyl acetate — UV, 1H-NMR, 13C-NMR Kaouadji et al. (1978)
12 Herpetotriol C30H32O9 Ethyl acetate — UV, 1H-NMR, 13C-NMR Kaouadji et al. (1978)
13 Herpepropenal C30H30O10 Ethyl acetate Silica gel column chromatography, RPC18, HPLC MS, 13C-NMR, 1H-NMR, DEPT, HMBC, COSY, HSQC, NOESY Yang et al. (2010)
14 7,8′-didehydlroherpetotriol C30H32O9 Ethyl acetate Reversed phase silica gel column chromatography, Preparation for HPLC Chromatography UV, IR, MS, 1H-NMR,13C-NMR Xu (2012)
15 (7S,8R,7′R,8′S)-7'-[7′-ethoxyl-7'-(4′-hydroxyl-3′-methoxylphenyl)]methyl-7-(4-hydroxyl-3-methoxylphenyl)-8-hydroxymethyl-tetrahydrofuran C22H28O7 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi- preparative HPLC UV, IR, 1H-NMR, 13C-NMR Ma (2020)
16 (7S,8R)-threo-1'-[3′-hydroxy-7-(4-hydroxy-3-methoxyphenyl)-8-hydroxymethyl-7,8-dihydrobenzofuran] acrylaldehyde C19H18O6 Ethyl aceta Normal phase silica gel column chromatography, MPLC, semi- preparative HPLC UV, IR, 1H-NMR, 13C-NMR Ma (2020)
17 (−)-Tanegool-7′-methyl etherl C21H26O7 Ethyl acetate Silica gel column chromatography, sephadex LH-20 MS, 1H-NMR, 13C-NMR Zhou (2014)
18 Herpetin C30H34O9 Ethyl acetate Silica gel column chromatography, Rp-Si -gel, semi- preparative HPLC MS, IR, 1H-NMR, 13C-NMR Yuan et al. (2005)
19 Lariciresino C20H24O6 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC UV, 1H-NMR,13C-NMR Ma (2020)
20 (+)-(7′S,7′′S,8′R,8′′R)-4,4′,4′′-Trihydroxy-3,5′,3′′-trimethoxy-7-oxo-8-ene[8-3′,7′-O-9′′,8′-8′′,9′-O-7′′] lignoid C30H30O9 Petroleum ether Silica gel column chromatography, preparative HPLC MS, IR, 1H-NMR, 13C-NMR, 1H-1H COSY, HMQC, HMBC Yu et al. (2014)
21 Ent-isolariciresinol C20H24O6 Ethyl acetate Silica gel column chromatography, MPLC, semi-preparative HPLC UV, MS, 1H-NMR, 13C-NMR Ma (2020)
22 Herpetenol C20H22O6 Ethyl acetate Silica gel column chromatography UV, IR, MS, 1H-NMR, 13C-NMR Wang (2005)
23 Herpetfluorenone C16H14O6 Ethyl acetate Silica gel column chromatography, sephadex LH-20 MS, 1H-NMR, 13C-NMR Gong et al. (2016)
24 (1S)-4hydroxy-3-[2-(4-hydroxy-3-methoxy-phenyl)-1-hydroxymethyl2-oxo-ethyl]-5-methoxy-benzaldehyde C18H18O7 Petroleum ether Silica gel column chromatography, RPC18, sephadex LH-20 MS, IR, 1H-NMR, 13C-NMR, 1H-1H COSY, HMQC, HMBC Yu et al. (2014)
25 Hedyotol A C30H32O9 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
26 Picrasmalignan C30H30O9 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
27 Balanophonin C20H20O6 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
28 1-Propanone, 3-hydroxy-1-(4-hydrpxy-3-methoxyphenyl)-2-[4-(3-hydroxy-1-propen-1-yl)-2-methoxyphenoxy] C21H24O6 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
29 Erythro-guaiacylglycerol-b-coniferyl ether C20H24O7 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
30 Threo-guaiacylglycerol- b-coiferyl ether C20H24O7 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
31 (7R,8S)-Dehydrodiconiferyl alcohol γ′- methyl ether C21H24O6 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
32 3-Benzofuranmethanol, 2, 3-dihydro-2-(4-dydroxy-3-methoxypenyl)-7-methoxy-5-(3-methoxyl-1-propenyl)-,[2S-[2a,3b, 5(E)]]-(9CI) C21H24O6 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
33 Evofolin-B C17H18O6 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
34 1-Propanon, 3-hydroxy-1-(2-hydrpxy-5-methoxyphenyl)-2-(4-hydroxy-3-methoxyphenyl)- C20H24O7 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
35 Herpetatol A C19H18O5 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
36 Herpetatol B C19H16O5 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
37 Herpetatol C C20H22O7 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
38 Herpetatol D C31H32O9 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
39 Herpetatol E C30H30O9 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
40 Herpetatol F C29H28O8 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
41 Herpetatol G C29H28O8 Ethyl acetate Silica gel/gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Hu (2016)
42 (−)-pinoresinol monomethyl ether C21H24O6 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC MS, IR,1H-NMR, 13C-NMR Ma (2020)
43 epipinoresinol C20H22O6 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC UV, MS, 1H-NMR, 13C-NMR Ma (2020)
44 (+)-pinoresinol C20H22O6 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC MS, IR, 1H-NMR, 13C-NMR Ma (2020)
45 (+)-menbrine C21H24O5 Ethyl acetate Normal phase silica gel column chromatography, semi-preparative HPLC MS, IR, 1H-NMR, 13C-NMR Ma (2020)
46 cinncassins D C28H28O9 Ethyl acetate Normal phase silica gel column chromatography, semi-preparative HPLC MS, UV, IR, 1H-NMR, 13C-NMR Ma (2020)
47 (7R,7′R,7″R,8S,8′S,8″S)-4′,4″-dihydroxy-3,3′,3″,5-tetramethoxy-7,9':7′,9-diepoxy-4,8″-oxy-8,8′-sesqoineolignan-7″,9″-diol C31H36O11 Ethyl acetate Normal phase silica gel column chromatography, MPLC, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Ma (2020)
48 3-Benzofuranmethanol-2,3-dihydro-2-(4-hydroxy-3-methoxyphenyl)-4-:methoxy-6-[tetra-hydro-2-(3-hydroxy-4-methoxyphenyl)-3-methanol]-2-furanmethyl C31H36O8 Ethyl acetate Normal phase silica gel column chromatograpy MS, 1H-NMR, 13C-NMR Yuan et al. (2006b)
49 Ehletianol C C30H36O10 Ethyl acetate Normal phase silica gel column chromatography, semi-preparative HPLC MS, UV, 1H-NMR, 13C-NMR Ma (2020)
50 Herpetosiol G C20H22O5 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HMBC Ma (2020)
51 Herpetosiol H C23H30O8 Ethyl acetate Normal phase silica gel column chromatography, sephadex LH-20, semi-preparative HPLC UV, IR, MS, 1H-NMR, 13C-NMR, HSQC, HMBC, COSY, NOESY Ma (2020)
52 Herpetosiol I C30H34O10 Ethyl acetate Normal phase silica gel column chromatography, sephadex LH-20, semi-preparative HPLC UV, IR, MS, 1H-NMR, 13C-NMR, HSQC, HMBC, COSY, NOESY Ma (2020)
53 Herpetosiol J C23H24O9 Ethyl acetate Normal phase silica gel column chromatography, semi-preparative HPLC UV, MS, 1H-NMR, 13C-NMR, HSQC, HMBC, COSY, NOESY Ma (2020)
54 Herpetosiol K C30H30O9 Ethyl acetate Normal phase silica gel column chromatography, semi-preparative HPLC UV, IR, MS, 1H-NMR, 13C-NMR, HSQC, HMBC, COSY, NOESY Ma (2020)
55 Herpetosiol L C19H18O6 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC UV, MS, 1H-NMR, 13C-NMR, HSQC, HMBC, COSY, NOESY Ma (2020)
56 Herpetosiol M C20H20O7 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HMBC Ma (2020)
57 Herpetosiol N C32H38O11 Ethyl acetate Normal phase silica gel column chromatography, MPLC, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HSQC, HMBC, COSY, NOESY Ma (2020)
58 Phyllanglaucin B C30H34O9 Ethyl acetate Normal phase silica gel column chromatography, recrystallization MS, 1H-NMR, 13C-NMR Huang et al. (2021)
59 Buddlenol E C32H38O10 Ethyl acetate Normal phase silica gel column chromatography, sephedax LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Huang et al. (2021)
60 Spathulated C30H34O9 Ethyl acetate — HPLC Wei et al. (2020)
61 Threo-buddlenol E C31H36O11 Ethyl acetate — HPLC Wei et al. (2020)
62 Picrasmalignan A C29H28O9 Ethyl acetate — HPLC Wei et al. (2020)
63 9,3′-Dimethoxyhierochin A C21H24O6 Ethyl acetate — HPLC Wei et al. (2020)
64 Sesquilignan C30H34O9 Ethyl acetate — HPLC Yuan et al. (2019)
65 Herpedulin A C50H52O16 Ethyl acetate Silica gel column chromatography, preparative TLC MS, 1H-NMR, 13C-NMR, HMBC Meng et al. (2022)
66 Herpedulin B C30H34O10 Ethyl acetate Silica gel column chromatography, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HMBC Meng et al. (2022)
67 Herpedulin C C31H36O11 Ethyl acetate Silica gel column chromatography, MPLC, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, 1H-1H COSY, HSQC, HMBC, CD spectrum Meng et al. (2022)
68 Herpedulin D C31H36O11 Ethyl acetate Silica gel column chromatography, MPLC, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, 1H-1H COSY, HSQC, HMBC, CD spectrum Meng et al. (2022)
69 Herpedulin E C30H30O9 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HMBC, CD spectrum Meng et al. (2022)
70 Herpedulin F C32H38O11 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HSQC, COSY Meng et al. (2022)
71 Herpedulin G C30H32O11 Ethyl acetate Silica gel column chromatography, MPLC, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HSQC, CD spectrum Meng et al. (2022)
72 Herpedulin H C30H32O11 Ethyl acetate Silica gel column chromatography, MPLC, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, CD spectrum Meng et al. (2022)
73 Herpedulin I C30H32O11 Ethyl acetate Silica gel column chromatography, MPLC, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, CD spectrum Meng et al. (2022)
74 Herpedulin J C23H24O9 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HSQC, NOSY, HMBC Meng et al. (2022)
75 Herpedulin K C30H26O9 Ethyl acetate Silica gel column chromatography, recrystalization MS, 1H-NMR, 13C-NMR, HSQC, HMBC Meng et al. (2022)
76 Herpedulin L C23H30O8 Ethyl acetate Silica gel column chromatography, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HMBC, NOESY, CD spectrum Meng et al. (2022)
77 Herpedulin M C19H18O6 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HSQC, 1H-1HCOSY, HMBC Meng et al. (2022)
78 Herpedulin N C20H20O7 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Meng et al. (2022)
79 Herpedulin O C20H22O5 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, HMBC, CD spectrum Meng et al. (2022)
80 Herpedulin P C19H20O5 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR CD spectrum Meng et al. (2022)
Fatty acids
81 Palmitic acid C16H32O2 Petroleum ether — GC-MS Liu et al. (2005a)
82 Oleic acid C18H34O2 Petroleum ether — GC-MS Liu et al. (2005a)
83 Stearic acid C18H34O2 Petroleum ether — GC-MS Liu et al. (2005a)
84 Linoleic acid C18H32O2 Petroleum ether — GC-MS Zhang et al. (2004)
85 Linolenic acid C18H30O2 Petroleum ether Normal phase silica gel column chromatography, semi- preparative HPLC MS, 1H-NMR, 13C-NMR Dong et al. (2019)
86 Trilinolein C57H98O6 Petroleum ether Normal phase silica gel column chromatography, preparative HPLC MS, 1H-NMR, 13C-NMR Dong et al. (2019)
87 9-Octadecenoic acid C18H34O2 Petroleum ether — GC-MS Liu et al. (2005b)
88 Octadecanoic acid C18H36O2 Petroleum ether — GC-MS Liu et al. (2005a)
89 cis-5-Dodecaenoic acid C12H22O2 Petroleum ethe Silica gel column chromatography MS, 1H-NMR, 13C-NMR Chen (2020)
90 Dodecanoic acid C12H24O2 Ethyl acetate Silica gel column chromatography MS, 1H-NMR, 13C-NMR Xu, (2012)
91 10-Eicossenoic acid C20H38O2 Ethyl acetate Silica gel column chromatography, sephadex LH-20 MS, 1H-NMR, 13C-NMR Xu, (2012)
Terpenoids
92 Neocucurbitacin D C31H44O8 90% EtOH Silica gel column chromatography, sephadex LH-20, RP-HLPC MS, IR, 1H-NMR, 13C-NMR, HMBC, NOESY Jiang et al. (2020)
93 Cucurbitacin E C32H44O8 90% EtOH Silica gel column chromatography, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Jiang et al. (2020)
94 Cucurbitacin D C30H44O7 90% EtOH Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Jiang et al. (2020)
95 Cucurbitacin B C31H44O8 90% EtOH Silica gel column chromatography, sephadex LH-20, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Jiang et al. (2020)
96 Cucurbitacin I C30H46O7 90% EtOH Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR, 13C-NMR Jiang et al. (2020)
97 23, 24-Dihydroisocucurbitacin B C32H48O8 90% EtOH Silica gel column chromatography, sephadex LH-20, RP-HLPC MS, 1H-NMR, 13C-NMR Jiang et al. (2020)
98 Cucurbitacin M C30H44O6 Ethyl acetate Normal phase silica gel column chromatography, MPLC, semi-preparative HPLC MS, 1H-NMR, 13C-NMR, DEPT, HMBC, 1H-H COSY Ma (2020)
99 Herpetosin A C22H30O6 Ethyl acetate Silica gel column chromatography UV, IR, MS, 13C-NMR, 1H-NMR Xu (2012)
100 Cucurbitacin L C30H44O7 Ethyl acetate Silica gel column chromatography, Sephadex LH-20 MS, 1H-NMR Dai et al. (2017)
101 Oleanic acid C30H48O3 Ethyl acetate Silica gel column chromatography, Sephadex LH-20 MS, 1H-NMR Dai et al. (2017)
Coumarins
102 Herpetolide A C16H14O6 Ethyl acetate Silica gel column chromatography, recrystallization MS, IR, 1H-NMR, 13C-NMR, HMBC, NOESY, DEPT, HMQC Zhang et al. (2008)
103 Herpetolide B C16H12O6 Ethyl acetate Silica gel column chromatography, recrystallization MS, IR, 1H-NMR, 13C-NMR, HMBC Zhang et al. (2008)
104 Herpetosperin A C22H24O11 Ethyl acetate Silica gel column chromatography, ODS silica gel CC, semi-preparative HPLC MS, IR, 1H-NMR, 13C-NMR, HMBC Xu et al. (2015)
105 Herpetosperin B C22H24O11 Ethyl acetate Silica gel column chromatography, ODS silica gel CC, semi-preparative HPLC MS, IR, 1H-NMR, 13C-NMR, HMBC Xu et al. (2015)
106 Herpetospin C C23H26O10 Ethyl acetate Reverse phase silica gel column chromatography UV, IR, MS, 13C-NMR, 1H-NMR Xu (2012)
107 Herpetolide H C19H16O6 Ethyl acetate Normal phase silica gel column chromatography, recrystallization MS, 1H-NMR, 13C-NMR Huang et al. (2021)
108 Herpetospin D C22H22O11 Ethyl acetate Normal phase silica gel column chromatography, recrystallization MS, 1H-NMR, 13C-NMR Xu (2012)
Others
109 Arginine C6H14N4O2 HCl — HITACHI 835-50 High-speed amino acid analyzer, XDY-I atomic fluorescence spectrometer Li et al. (2005)
110 Histidine C6H9N3O2 HCl — HITACHI 835-50 High-speed amino acid analyzer, XDY-I atomic fluorescence spectrometer Li et al. (2005)
111 Lysine C6H14N2O2 HCl — HITACHI 835-50 High-speed amino acid analyzer, XDY-I atomic fluorescence spectrometer Li et al. (2005)
112 Leucine C6H13NO2 HCl — HITACHI 835-50 High-speed amino acid analyzer, XDY-I atomic fluorescence spectrometer Li et al. (2005)
113 Isoleucine C6H13NO2 HCl — HITACHI 835-50 High-speed amino acid analyzer, XDY-I atomic fluorescence spectrometer Li et al. (2005)
114 Tryptophan C11H12N2O2 HCl — HITACHI 835-50 High-speed amino acid analyzer, XDY-I atomic fluorescence spectrometer Li et al. (2005)
115 Kaempferitrin C27H30O14 Ethyl acetate Reversed phase silica gel column chromatography, semi-preparative HPLC UV, IR, 1H-NMR, 13C-NMR Fan et al. (2016)
116 3′-Hydroxydaidzein C15H10O5 Ethyl acetate Silica gel column chromatography, semi-preparative HPLC MS, 1H-NMR Dai et al. (2017)
117 Stigmasterol C29H48O Ethyl acetate Silica gel column chromatography, recrystalization MS, 1H-NMR, 13C-NMR Liu et al. (2010)
118 β-Stigmasterol C29H48O Ethyl acetate Silica gel column chromatography, Sephadex LH-20 MS, 1H-NMR, 13C-NMR Gong (2013)
119 Spinasterol glucoside C35H56O6 Ethyl acetate Silica gel column chromatography, recrystalization UV, IR, MS, 1H-NMR, 13C-NMR Liu et al. (2010)
120 Arbutin, 1-acetate C14H18O8 Ethyl acetate Reversed phase silica gel column chromatography Uv, IR, MS, 1H-NMR, 13C-NMR Hu (2016)
121 Herpetolide C C16H14O6 Petroleum ether Silica gel column chromatography, sephadex LH-20, smi-preparative HPLC UV, IR, MMS, 1H-NMR, 13C-NMR, HMQC, HMBC Fan et al. (2016)
122 Eicosanoic acid, 2-propenyl ester C23H44O2 Ethyl acetate Silica gel column chromatography, sephadex LH-20 MS, 1H-NMR Dai et al. (2017)
123 3-Dodecen-1-yne C12H20 petroleum ether — GC-MS Liu et al. (2005)
124 2,6,10,14,18,22-Tetracosahexaen C24H38 petroleum ether — GC-MS Zhang et al. (2004)
125 Herpecaudin C17H22O4 Ethyl acetate RPHPLC, silica gel column chromatography, RP-18, sephadex LH-20 MS,1H-NMR,13C-NMR, HMBC, NOESY, CD spectrum, X-ray Jiang et al. (2016)