Table 1. Binding Constants of CP·WP6 and CP·WP5 Complexes.
complex | K [M–1] | method of determination |
---|---|---|
trans-CP·WP5 | (4.3 ± 1) × 103 | absorption spectroscopy |
(2.77 ± 0.05) × 103 | fluorescence spectroscopy | |
(3.2 ± 0.3) × 103 | NMR | |
(trans-CP)2·WP5 | (8 ± 3) × 102 | NMR |
cis-CP·WP5 | (1.4 ± 0.8) × 103 | absorption spectroscopy |
trans-CP·WP6 | (1.37 ± 0.18) × 105 | absorption spectroscopy |
(1.45 ± 0.07) × 105 | fluorescence spectroscopy | |
(1.6 ± 0.2) × 105 | isothermal calorimetry | |
(trans-CP)2·WP6 | (9.2 ± 2) × 103 | isothermal calorimetry |
cis-CP·WP6 | (1.31 ± 0.18) × 105 | absorption spectroscopy |