. 2025 Jan 4;16:392. doi: 10.1038/s41467-024-55620-0

Table 1.

Photophysical and electrochemical data, and yields for intrinsic degradation of the MR-TADF dopants

	λ_em (nm)^a,b	Φ_PL (%)^a,c	τ_PF (ns) ^a,d	τ_DF (μs) ^a,e	k_r^TADF (10⁴ s⁻¹)^f	k_rISC (10⁵ s⁻¹)^g	E_T1 (eV)^a,h	ΔE_ST (eV)^a,i	E_ox (V vs SCE)^j	Φ_deg (%)^k	Faradaic yield (%)^l
1	471	96	11	78	5.1	1.8	2.49	0.27	0.98	0.29	37
2	467	98	6	3.8	6.3	6.2	2.64	0.11	0.92	0.92	46
3	461	98	7	28	5.6	4.1	2.57	0.21	0.97	0.68	59
4	459	100	5	111	5.4	1.1	2.54	0.25	0.90	0.22	79
1D	473	94	10	62	5.5	1.5	2.49	0.24	0.95	0.18	30

^a2 wt% in PMMA films, 300 K. See Supplementary Fig. 1 for the UV−Vis absorption and photoluminescence spectra recorded in tetrahydrofuran (THF).

^bEmission peak wavelength. See Supplementary Fig. 2 for the photoluminescence spectra of the PMMA films.

^cPhotoluminescence quantum yield determined absolutely using an integrating sphere.

^dLifetime of prompt fluorescence.

^eLifetime of delayed fluorescence.

^fRadiative rate constant, k_r^TADF = Φ_PL/τ_obs, where τ_obs is the average fluorescence lifetime.

^gRate constant for reverse intersystem crossing, k_rISC = (Φ_total × k_PF × k_DF)/k_r^S1.

^hEnergy of the triplet state.

ⁱThe energy difference between the singlet and the triplet excited states. Refer to Supplementary Fig. 3 for details.

^jOxidation potential determined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) for Ar-saturated THF containing 1.0 mM dopant and 0.10 M tetrabutylammonium hexafluorophosphate; A glassy carbon disk and a Pt wire for the working and counter electrodes, respectively; an Ag/AgNO₃ pseudo-reference electrode; scan rates = 0.1 V s ⁻¹ (CV) and 4 mV s ⁻¹ (DPV). See Supplementary Fig. 4 for the voltammograms.

^kQuantum yield for photolysis.

^lFaradaic yield for oxidative bulk electrolysis.