Table 4. Experimental details.
| Crystal data | |
| Chemical formula | [Co(C5H5N2O2S2)2(H2O)4] |
| M r | 509.45 |
| Crystal system, space group | Monoclinic, P21/c |
| Temperature (K) | 293 |
| a, b, c (Å) | 5.1950 (2), 10.0347 (3), 18.9090 (6) |
| β (°) | 91.892 (3) |
| V (Å3) | 985.19 (6) |
| Z | 2 |
| Radiation type | Cu Kα |
| μ (mm−1) | 11.23 |
| Crystal size (mm) | 0.08 × 0.06 × 0.04 |
| Data collection | |
| Diffractometer | Xcalibur, Ruby |
| Absorption correction | Multi-scan (CrysAlis PRO; Rigaku OD, 2021 ▸) |
| Tmin, Tmax | 0.808, 1.000 |
| No. of measured, independent and observed [I > 2σ(I)] reflections | 6554, 2023, 1770 |
| R int | 0.055 |
| (sin θ/λ)max (Å−1) | 0.630 |
| Refinement | |
| R[F2 > 2σ(F2)], wR(F2), S | 0.038, 0.098, 1.06 |
| No. of reflections | 2023 |
| No. of parameters | 137 |
| No. of restraints | 1 |
| H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) | 0.34, −0.27 |