Table 2.

Phenanthrolinium-Catalyzed Stereoselective Glycosylations with Alcohols^a

^aReactions were conducted with donor (0.12 mmol) and acceptor (0.10 mmol) in Et₂O (0.2 M).

^bIsolated yields are reported.

^cThe α:β ratios were determined by ¹H NMR.

^dReactions were conducted with 5 mol % TMSOTf at 0 °C for 1 h.

^eReactions were conducted at 25 °C for 24 h.

^fA 1:1 mixture of Et₂O and DCM was used as a solvent.

^gReactions were conducted with 15 mol % [PhenH]⁺[BF₄]⁻ at 25 °C for 24 h.