Table 1.
Performance of the CCDs in comparison with recently reported results
| # | Performance | Electrolyte and temperature | Electrodes and diaphragm | Reference |
|---|---|---|---|---|
| 1 |
1.78 V @ 0.5 A cm−2 1.98 V @ 1.0 A cm−2 |
30 wt% KOH at 90 oC | Raney Ni-Mo sprayed perforated Ni sheet anode/cathode and Dapozol membrane | 9 |
| 2 |
1.7–1.73 V @ 0.5 A cm-2 1.83–1.90 V @ 1.0 A cm-2 |
30 wt% KOH at 80 oC | Raney Ni foam cathode, Ni-Fe-LDH decorated Fe foam anode, and Al2O3:ZrO2/PSU composite diaphragm | 41 |
| 3 | 1.8 V @ 0.5 A cm-2 | 28 wt% KOH at 80 oC | Ni–Mo-coated expanded Nickel grids cathode, NiCo2O4-coated expanded Nickel grids anode, and PSU/PVP/TiO2 composite diaphragm | 17 |
| 4 |
1.65 V @ 0.5 A cm−2 1.78 V @ 1.0 A cm-2 |
30 wt% KOH at 80 oC | Raney Ni foam cathode, Ni-Fe-LDH decorated Fe foam anode, and cellulose nanocrystals blended ZrO2/PSU diaphragm | 42 |
| 5 |
1.74 V @ 0.5 A cm-2 1.98 V @ 1.0 A cm-2 |
30 wt% KOH at 80 oC | Raney Ni foam cathode, Ni-Fe-LDH decorated Fe foam anode, and Zirfon diaphragm | 42 |
| 6 | 1.83 V @ 0.3 A cm-2 | 6 M KOH at 75 oC | Raney Ni plate cathode, stainless steel 316 L plate anode, and Zirfon 500 diaphragm | 43 |
| 7 |
1.68 V @ 0.5 A cm-2 1.80 V @ 1.0 A cm-2 |
30 wt% KOH at 80 oC | Raney Ni foam cathode, Ni-Fe-LDH decorated Ni foam anode, and ZrO2/PSU composite 300 μm diaphragm | 13 |
| 8 |
1.78 V @ 0.5 A cm-2 1.98 V @ 1.0 A cm-2 |
30 wt% KOH at 80 oC | Raney Ni foam cathode, Ni-Fe-LDH decorated Ni foam anode, and Zirfon diaphragm | 13 |
| 9 |
1.86 V @ 0.5 A cm−2 2.1 V @ 1.0 A cm−2 |
30 wt% KOH at 80 oC | Raney Ni mesh cathode, CoMnO@CoFe-LDH decorated Ni foam anode, and Zirfon 500 diaphragm | 44 |
| 10 | 1.95 V @ 1.0 A cm-2 | 30 wt% KOH at 80 oC | Raney Ni mesh cathode, CoMnO@CoFe-LDH decorated Ni foam anode, and diethanolamine functionalized ZrO2/PSU diaphragm | 44 |
| 11 |
1.85 V @ 0.5 A cm-2 2.1 V @ 1.0 A cm-2 |
32.5 wt% KOH at 80 oC | Raney Ni coated Zirfon diaphragm with per-oxidized Ni foam anode | 25 |
| 12 |
1.72 V @ 0.5 A cm-2 1.83 V @ 1.0 A cm-2 |
30 wt% KOH at 80 oC | Raney Ni coated Zirfon 220 diaphragm | This work |
| 13 |
1.64 V @ 0.5 A cm−2 1.8 V @ 1.0 A cm-2 |
30 wt% KOH at 80 oC | Pt/C and Ni-Fe LDH coated Zirfon 220 diaphragm | This work |
All voltages are non-iR corrected to demonstrate practical electrolysis performance.