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. 2025 Feb 3;16(6):1478–1484. doi: 10.1021/acs.jpclett.4c03636

Table 1. Peak Electron Detachment Energies (eDE) and PECD Measured at the Maximum of Each Peak (A–C) at Four Photon Energies (hν) for the R Enantiomer.

eDE (eV)
A B C
2.23 2.39 2.53
  PECD (%)
hν (eV) A B C
3.49 –4.9 ± 2.0 (6.3 ± 1.3)a 1.9 ± 1.3 (−1.1 ± 0.3)a 3.8 ± 1.5 (−3.5 ± 0.8)a
2.76 –3.8 ± 0.1 0.0 ± 0.4 1.7 ± 0.7
2.53 1.0 ± 0.2 3.1 ± 0.6  
2.38 3.5 ± 0.1    
a

S enantiomer measurement shown in parentheses.