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. 2024 Oct 27;46(4):2400786. doi: 10.1002/marc.202400786

Table 3.

Solution phase cyclic voltammetry data obtained in CH2Cl2.

Compound BF2 Reductions a) , b) FL/Bn Reduction a) , b)
E red1 [V] E red2 [V] E red3 [V]
Ph‐BF2‐Ph ‒0.75 ‒1.63
Ph‐FL‐Ph ‒2.35 c)
Ph‐Bn‐Ph ‒2.34 c)
BF2‐BF2‐BF2 ‒0.74, ‒0.85 ‒1.66, ‒1.85
P‐FL
P‐Bn ‒2.05
P‐BF2‐FL ‒0.75 ‒1.62 ‒2.35 c)
P‐BF2‐Bn ‒0.75 ‒1.62 ‒2.32 c)
P‐FL‐Bn
a)

All potentials are reported relative to the Fc/Fc+ redox couple;

b)

Hyphens indicate that no redox activity was observed; and

c)

Irreversible process, potential at maximum cathodic current reported.