Table 3.
IR spectrum signals for ClMPcs in KBr pellet and film on n-type Si.
| Sample | C-H | C-C | OH | C=C | C=N | C-N | α-form | β-form |
|---|---|---|---|---|---|---|---|---|
| TiPcCl2 KBr pellet | 3055, 1424, 1121, 907, 780-720 | 1647, 1330, 1162 | 3428 | 1610 | 1465 | 1288, 1069 | – | 732 |
| TiPcCl2 film | 3053, 1423, 1121, 907, 789-700 | 1647, 1335, 1167 | 3465 | 1610 | 1470 | 1288, 1069 | – | 730 |
| MnPcCl KBr pellet |
3054, 1418, 1118, 907, 789-700 | 1647, 1336, 1168 | 3480–3440 | 1606 | 1461 | 1287, 1076 | – | 729 |
| MnPcCl film | 3059, 1422, 1118, 907, 780-720 | 1658, 1336, 1168 | 348 | 1602 | 1461 | 1287, 1061 | – | 727 |
| InPcCl KBr pellet | 3049, 1421, 1113, 896, 782-710 | 1651, 1334, 1161 | – | 1606 | 1466 | 1285, 1060 | 725 | – |
| InPcCl film | 3049, 1421, 1113, 887, 790-700 | 1651, 1338, 1160 | – | 1607 | 1466 | 1280, 1062 | 722 | – |
| AlPcCl KBr pellet | 3053, 1422, 1118, 901, 782-702 | 1651, 1333, 1166 | 3441 | 1604 | 1466 | 1289, 1062 | – | 728 |
| AlPcCl film | 3049, 1426, 1118, 901, 777-711 | 1647, 1343, 1166 | – | 1612 | 1466 | 1286, 1062 | – | 731 |