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. 2025 Feb 14;11(4):e42697. doi: 10.1016/j.heliyon.2025.e42697

Table 3.

IR spectrum signals for ClMPcs in KBr pellet and film on n-type Si.

Sample C-H C-C OH C=C C=N C-N α-form β-form
TiPcCl2 KBr pellet 3055, 1424, 1121, 907, 780-720 1647, 1330, 1162 3428 1610 1465 1288, 1069 732
TiPcCl2 film 3053, 1423, 1121, 907, 789-700 1647, 1335, 1167 3465 1610 1470 1288, 1069 730
MnPcCl
KBr pellet
3054, 1418, 1118, 907, 789-700 1647, 1336, 1168 3480–3440 1606 1461 1287, 1076 729
MnPcCl film 3059, 1422, 1118, 907, 780-720 1658, 1336, 1168 348 1602 1461 1287, 1061 727
InPcCl KBr pellet 3049, 1421, 1113, 896, 782-710 1651, 1334, 1161 1606 1466 1285, 1060 725
InPcCl film 3049, 1421, 1113, 887, 790-700 1651, 1338, 1160 1607 1466 1280, 1062 722
AlPcCl KBr pellet 3053, 1422, 1118, 901, 782-702 1651, 1333, 1166 3441 1604 1466 1289, 1062 728
AlPcCl film 3049, 1426, 1118, 901, 777-711 1647, 1343, 1166 1612 1466 1286, 1062 731