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. 2025 Feb 18;10(8):8462–8471. doi: 10.1021/acsomega.4c10622

Table 2. Synthesis of Aromatic Thioesters.

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a

Smaller amounts of 1-dodecanethiol (1.05 equiv) and iPrMgCl (1.05 equiv) were used.

b

1 equiv of iPrMgCl was added to deprotonate the N–H bond at 0 °C prior to the thioesterification.

c

1.5 equiv of iPrMgCl was added to deprotonate the O–H bond at 0 °C prior to the thioesterification at 60 °C.