Table 2.
Experimental (xe) and ideal solubility (xidl) values of RCB in different {PEG 400 + water} mixes (PEG 400 mass fraction m = 0.0–1.0) at 293.2–313.2 K and 101.1 kpa
| ma | xeb | ||||
|---|---|---|---|---|---|
| T = 293.2 K | T = 298.2 K | T = 303.2 K | T = 308.2 K | T = 313.2 K | |
| 0.0 | 1.14 × 10− 5 | 1.41 × 10− 5 | 1.68 × 10− 5 | 2.11 × 10− 5 | 2.41 × 10− 5 |
| 0.1 | 2.29 × 10− 5 | 2.84 × 10− 5 | 3.41 × 10− 5 | 4.29 × 10− 5 | 4.90 × 10− 5 |
| 0.2 | 4.51 × 10− 5 | 5.59 × 10− 5 | 6.79 × 10− 5 | 8.51 × 10− 5 | 9.89 × 10− 5 |
| 0.3 | 8.91 × 10− 5 | 1.13 × 10− 4 | 1.39 × 10− 4 | 1.74 × 10− 4 | 2.02 × 10− 4 |
| 0.4 | 1.78 × 10− 4 | 2.24 × 10− 4 | 2.73 × 10− 4 | 3.42 × 10− 4 | 4.05 × 10− 4 |
| 0.5 | 3.51 × 10− 4 | 4.40 × 10− 4 | 5.47 × 10− 4 | 6.82 × 10− 4 | 8.17 × 10− 4 |
| 0.6 | 6.90 × 10− 4 | 8.68 × 10− 4 | 1.11 × 10− 3 | 1.41 × 10− 3 | 1.72 × 10− 3 |
| 0.7 | 1.39 × 10− 3 | 1.74 × 10− 3 | 2.20 × 10− 3 | 2.74 × 10− 3 | 3.37 × 10− 3 |
| 0.8 | 2.72 × 10− 3 | 3.43 × 10− 3 | 4.37 × 10− 3 | 5.47 × 10− 3 | 6.73 × 10− 3 |
| 0.9 | 5.37 × 10− 3 | 6.79 × 10− 3 | 8.71 × 10− 3 | 1.12 × 10− 2 | 1.38 × 10− 2 |
| 1.0 | 1.05 × 10− 2 | 1.34 × 10− 2 | 1.73 × 10− 2 | 2.17 × 10− 2 | 2.73 × 10− 2 |
| x idl | 2.86 × 10− 1 | 2.99 × 10− 1 | 3.13 × 10− 1 | 3.27 × 10− 1 | 3.41 × 10− 1 |
aThe uncertainties u are u(T) = 0.15 K, u(m) = 0.0007, and u(p) = 2 kPa, and bthe relative uncertainty ur in solubility is ur(xe) = 0.05