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. 2025 Apr 2;15(13):10049–10073. doi: 10.1039/d4ra07932a

Table 2. Recent studies focused on enhancing PCM performance using supporting structures.

Support PCM Details Results Application Reference
Graphene nanoplatelets/cellulose aerogel PEG 6000 Freeze-drying/(−55 °C) and impregnation under vacuum/(80 °C, 24 h) The fabricated aerogel had a density of 0.06–0.12 g cm−3 with 89–95% open units Thermal energy storage (TES) 20
Morphological analysis showed no clear interface between the aerogel network and PEG in the composite, indicating good compatibility, which enhanced thermal conductivity, mechanical properties, and shape stability (up to 100 °C)
Thermal conductivity increased with higher graphite content, while graphite fillers reduced PCM's melting enthalpy by disrupting molecular bonding
Crystalline nanocellulose PEG 2000 Radical polymerization/(80 °C, 4–16 h) The composite samples maintained thermal and shape stability up to 300 °C for 120 cycles, with lower enthalpy and minimal leakage compared to pure PCM Smart heat storage 21
Novolac/carbon monofilament/zinc borate aerogel Paraffin wax (PW) Sol–gel polymerization/(120 °C, 5 h) and impregnation/(120 °C, 48 h) The addition of conductive fillers and zinc borate increased aerogel porosity while enhancing thermal conductivity Free cooling in electrical industry 16
Higher zinc borate content reduced polarity and compatibility with PW, decreasing impregnation
AC0Z0 (75 wt% PW) showed no leakage, while nanocomposite aerogels (77 wt% PW) had minimal leakage, even after 10 heating–cooling cycles. Leakage below 2.59 wt% confirmed effective PW impregnation and retention