The component peaks are the result of curve fitting using a Gaussian line shape. The sums of the fitted components superimpose on the experimental amide I region spectra. A molar ratio of approx. 1:30 was used. ———, deconvoluted amide I region spectra; -----, fitted structural components. (A) [D]-L6K6, (B) [D]-L6K6-DA, (C) [D]-L6K6-DDA, (D) [D]-L6K6-MA and (E) [D]-L6K6-PA.