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. 2025 Apr 14;16(20):8764–8771. doi: 10.1039/d5sc01726b

Table 1. Selected bond lengths (Å) and angles (°), and tetrahedral characters (THC) (%).

Compound B–S bond lengths/Å Σ(C–B–C)/° THC/%
cis-1a B1–S1 2.161(1) 350.2 31.1
B2–S2 2.161(1) 350.2 31.1
cis-1ba A B1–S1 2.181(2) 350.6 29.8
B2–S2 2.231(3) 353.4 21.0
B B1–S1 2.146(3) 351.0 28.6
B2–S2 2.381(3) 354.4 17.8
trans-2a B1–S1/B2–S2 2.228(4) 353.5 20.7
trans-2b B1–S1/B2–S2 2.289(2) 355.1 15.6
a

cis-1b contains two crystallographically independent molecules A and B in the unit cell.