Table 1. Selected bond lengths (Å) and angles (°), and tetrahedral characters (THC) (%).
| Compound | B–S bond lengths/Å | Σ(C–B–C)/° | THC/% | ||
|---|---|---|---|---|---|
| cis-1a | B1–S1 | 2.161(1) | 350.2 | 31.1 | |
| B2–S2 | 2.161(1) | 350.2 | 31.1 | ||
| cis-1ba | A | B1–S1 | 2.181(2) | 350.6 | 29.8 |
| B2–S2 | 2.231(3) | 353.4 | 21.0 | ||
| B | B1–S1 | 2.146(3) | 351.0 | 28.6 | |
| B2–S2 | 2.381(3) | 354.4 | 17.8 | ||
| trans-2a | B1–S1/B2–S2 | 2.228(4) | 353.5 | 20.7 | |
| trans-2b | B1–S1/B2–S2 | 2.289(2) | 355.1 | 15.6 | |
cis-1b contains two crystallographically independent molecules A and B in the unit cell.