Table 1. Formic Acid Decomposition Post-mortem Particle Size (Obtained from TEM) and Catalyst Loading (Obtained from ICP-OES)a.
| tertiary amine | particle size (TEM) [nm] | catalyst loading [wt %] |
|---|---|---|
| triethylamine | 4.69 ± 1.84 | 1.17 ± 0.05 |
| tributylamine | 5.78 ± 3.26 | 1.14 ± 0.03 |
| trihexylamine | 5.45 ± 2.22 | 1.15 ± 0.07 |
| N,N-dimethylbenzylamine | 4.50 ± 1.68 | 1.17 ± 0.02 |
| 2-(dimethylamino)ethanol | 4.98 ± 1.74 | 1.09 ± 0.07 |
| methyldiethanolamine | 4.41 ± 1.32 | 1.11 ± 0.05 |
| 6-dimethylamino-1-hexanol | 4.32 ± 1.10 | 1.15 ± 0.03 |
| 1-(3-dimethylaminophenyl)ethanol | 6.95 ± 1.92 | 1.10 ± 0.09 |
The reaction time was 4 h at 50 degrees Celsius. The initial particle size was established to be 2.6 ± 0.8 nm, and the loading was 1.21 wt %. For the TEM, at least 50 particles were analyzed for each sample. The average particle size of the fresh catalyst was confirmed by using CO pulse chemisorption (2.63 nm).