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. 2025 Apr 10;64(16):8109–8118. doi: 10.1021/acs.iecr.4c04902

Table 1. Formic Acid Decomposition Post-mortem Particle Size (Obtained from TEM) and Catalyst Loading (Obtained from ICP-OES)a.

tertiary amine particle size (TEM) [nm] catalyst loading [wt %]
triethylamine 4.69 ± 1.84 1.17 ± 0.05
tributylamine 5.78 ± 3.26 1.14 ± 0.03
trihexylamine 5.45 ± 2.22 1.15 ± 0.07
N,N-dimethylbenzylamine 4.50 ± 1.68 1.17 ± 0.02
2-(dimethylamino)ethanol 4.98 ± 1.74 1.09 ± 0.07
methyldiethanolamine 4.41 ± 1.32 1.11 ± 0.05
6-dimethylamino-1-hexanol 4.32 ± 1.10 1.15 ± 0.03
1-(3-dimethylaminophenyl)ethanol 6.95 ± 1.92 1.10 ± 0.09
a

The reaction time was 4 h at 50 degrees Celsius. The initial particle size was established to be 2.6 ± 0.8 nm, and the loading was 1.21 wt %. For the TEM, at least 50 particles were analyzed for each sample. The average particle size of the fresh catalyst was confirmed by using CO pulse chemisorption (2.63 nm).