Table 1. Association Constants (Ka) for Binding of Dodecaborate Anions to γ-CD, δ-CD, or ε-CDa.
|
Ka (M–1) for dodecaborate guestsb |
||||
|---|---|---|---|---|
| Host | B12Cl122– | B12Br122– | B12I122– | |
| γ-CD | Ka (1:1) | 2.6 × 104 | 5.5 × 104 | 2.4 × 105 |
| Ka (2:1) | 1.9 × 104 | 2.1 × 106 | 2.1 × 104 | |
| δ-CDc | Ka (1:1) | 8.7 × 106 | 1.2 × 107 | 9.2 × 105 |
| ε-CD | Ka (1:1) | 2.7 × 104 | 2.3 × 105 | 3.4 × 106c |
Determined by 1H NMR spectroscopy titration in D2O, unless stated otherwise. Uncertainties on the fits are given in Section S9.
All as their disodium salts.
Determined by ITC in H2O.