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. 2025 Apr 13;30(8):1744. doi: 10.3390/molecules30081744
A pre-exponential factor or Arrhenius factor in mole fr.−1·min−1
AAc acetic acid
Ea activation energy, J·mol−1
GC gas chromatography
ΔrH standard enthalpy of the reaction, J·mol−1
HFBAc 2,2,3,3,4,4,4-heptafluorobutyl acetate
HFBol 2,2,3,3,4,4,4-heptafluorobutan-1-ol
Keq chemical equilibrium constant
k1 rate constant of the forward reaction in mole fr.−1·min−1
k2 rate constant of the reverse reaction in mole fr.−1·min−1
M the molar mass in g·mol−1
m sample weight in g
NMR nuclear magnetic resonance
n number of parallel experiments
R gas constant, 8.314 J·mol−1·K−1
ΔrS standard entropy of the reaction, J·mol−1·K−1
T temperature in K or in °C
u standard uncertainty
v reaction rate in mol min−1
xi mole fraction of component i
xi0 the mole fraction of component i at τ = 0
σ combined standard uncertainty
τ1/2 half-reaction time in min
τ reaction time in min or hour or day
indexes
av the average value
i component index