Table 2. CV and EIS data produced from the experimental work in Fig. 8 for the synthesized materials modified SPEsa.
| Electrode type | I a (μA) | I c (μA) | E oxd. (V) | E red. (V) | E 1/2 (V) | R s (Ω) | R ct (1) (Ω) | CPE | n μF | W (Ω) | Cs (F g−1) |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Bare (unmodified SPE) | 19.1 | −21.5 | 0.22 | 0.093 | 0.165 | 102.3 | 1150 | 10.5 | 0.89 | 178 | — |
| 0% W | 65.2 | −92.3 | 0.21 | 0.078 | 0.144 | 101.2 | 450 | 15.3 | 0.85 | 120.3 | 1114.2 |
| 0.5% W | 123.6 | −149.6 | 0.25 | 0.083 | 0.16 | 100.1 | 352.3 | 16.5 | 0.78 | 117.2 | 1592.8 |
| 1.5% W | 203.5 | −181.3 | 0.32 | −0.016 | 0.152 | 50.3 | 120.6 | 17.3 | 0.84 | 111.6 | 2178.5 |
| 2% W | 243.6 | −240.9 | 0.20 | 0.08 | 0.14 | 99.8 | 90.2 | 19.8 | 0.87 | 95.8 | 1764.2 |
| 2.5% W | 86.2 | −62.1 | 0.194 | 0.068 | 0.13 | 100.3 | 420 | 15.9 | 0.89 | 118.4 | 828.5 |
I a: anodic current, Ic: cathodic current, Eoxd: potential of oxidation Ered: potential of reduction, Rs: solution resistance, Rct: charge transfer resistance, CPE: constant phase element, W: Warburg resistance, C is specific capacitance of the electrodes at scan rate of 50 mV s−1.