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. 2025 May 12;15(20):15670–15693. doi: 10.1039/d5ra01248a

Table 2. CV and EIS data produced from the experimental work in Fig. 8 for the synthesized materials modified SPEsa.

Electrode type I a (μA) I c (μA) E oxd. (V) E red. (V) E 1/2 (V) R s (Ω) R ct (1) (Ω) CPE n μF W (Ω) Cs (F g−1)
Bare (unmodified SPE) 19.1 −21.5 0.22 0.093 0.165 102.3 1150 10.5 0.89 178
0% W 65.2 −92.3 0.21 0.078 0.144 101.2 450 15.3 0.85 120.3 1114.2
0.5% W 123.6 −149.6 0.25 0.083 0.16 100.1 352.3 16.5 0.78 117.2 1592.8
1.5% W 203.5 −181.3 0.32 −0.016 0.152 50.3 120.6 17.3 0.84 111.6 2178.5
2% W 243.6 −240.9 0.20 0.08 0.14 99.8 90.2 19.8 0.87 95.8 1764.2
2.5% W 86.2 −62.1 0.194 0.068 0.13 100.3 420 15.9 0.89 118.4 828.5
a

I a: anodic current, Ic: cathodic current, Eoxd: potential of oxidation Ered: potential of reduction, Rs: solution resistance, Rct: charge transfer resistance, CPE: constant phase element, W: Warburg resistance, C is specific capacitance of the electrodes at scan rate of 50 mV s−1.