Table 2.
Thermal properties of PAIs.
| Polymer Code | Tg (°C) a | Td at 5% Weight Loss (°C) b | Td at 10% Weight Loss (°C) b | Char Yield (wt %) c | ||
|---|---|---|---|---|---|---|
| N2 | Air | N2 | Air | |||
| 6a | 355 | 525 | 537 | 553 | 575 | 58 |
| 6b | 326 | 545 | 550 | 578 | 600 | 60 |
| 6c | 304 | 532 | 539 | 576 | 589 | 55 |
| 6d | 296 | 504 | 488 | 541 | 549 | 58 |
| 6e | 331 | 496 | 514 | 523 | 559 | 58 |
| 6f | 326 | 549 | 535 | 585 | 576 | 62 |
| MeO-6a | 325 | 464 | 438 | 495 | 469 | 68 |
| MeO-6b | 323 | 483 | 482 | 519 | 520 | 66 |
| MeO-6c | 299 | 500 | 476 | 532 | 522 | 50 |
| MeO-6d | 286 | 501 | 473 | 539 | 509 | 60 |
| MeO-6e | 300 | 444 | 447 | 562 | 478 | 52 |
| MeO-6f | 326 | 480 | 473 | 522 | 511 | 55 |
| t -Bu-6a | 350 | 527 | 515 | 560 | 554 | 58 |
| t -Bu-6b | 304 | 513 | 522 | 549 | 556 | 58 |
| t -Bu-6c | 309 | 479 | 473 | 512 | 522 | 55 |
| t -Bu-6d | 289 | 501 | 509 | 532 | 554 | 56 |
| t -Bu-6e | 313 | 423 | 437 | 448 | 471 | 50 |
| t -Bu-6f | 322 | 511 | 486 | 552 | 525 | 58 |
a Midpoint temperature of the baseline shift on the second DSC heating trace (rate = 20 °C/min) after quenching from 400 to 50 °C in nitrogen. b Decomposition temperature at which a 5% or 10% weight loss was recorded by TGA at a heating rate of 20 °C/min and a gas flow rate of 20 cm3/min. c Residual weight % at 800 °C at a scan rate 20 °C/min in nitrogen.