. 2025 Apr 30;44(9):1006–1011. doi: 10.1021/acs.organomet.5c00095

Table 2. Catalytic Performance of PN- and PP-Based Mn(I) Methyl Complexes in the Dimerization of Phenylacetylene^a.

catalyst	conversion [%]	Z/E
PN1	75	95:5
PN2	35	96:4
PN3	14	90:10
PN4	12	90:10
PN5	n.d.	n.d.
PN7	n.d.	n.d.
PN6	trace	n.d.
PN8	n.d.	n.d.
PP3^b	>99	96:4
PP2^b	67	79:21
PP4	36	91:9
PP5	n.d	n.d.
none	n.d	n.d.

Reaction conditions: phenylacetylene (0.600 mmol, 1.00 equiv), catalyst (0.012 mmol, 2.00 mol %), THF (1 M), 80 °C for 18 h; conversion, E/Z ratio detected by GC-MS, n.d. = not detected.

Data taken from ref (17).

Table 2. Catalytic Performance of PN- and PP-Based Mn(I) Methyl Complexes in the Dimerization of Phenylacetylenea.

Table 2. Catalytic Performance of PN- and PP-Based Mn(I) Methyl Complexes in the Dimerization of Phenylacetylene^a.