2. Formal Atom Pair Swap via Photoinduced One-Electron IDcA of Allyl Esters with Olefin Acceptors .

^aAllyl ester (0.20 mmol), olefin acceptor (1.20 equiv), Pd₂(dba)₃ (1.25 mol %), L1 (3.75 mol %), PC1 (1 mol %), and K₂CO₃ (1 equiv) in DMF (0.1 M) at 20 °C under 451 nm blue LED irradiation (1 W) for 12–18 h. Isolated yields are an average of at least two independent runs.

^b4 h reaction time.

^c PC1 (2.5 mol %).

^dPd₂(dba)₃ (2.5 mol %) and L1 (7.5 mol %).

^e5 mmol scale with two 427 nm Kessil lamp irradiation (45 W) for 18 h.

^f PC1 (5.0 mol %) with 427 nm 45W blue-LED irradiation for 72 h.

^g 2a (3.0 equiv).

^hUtilizing 4CzIPN (2.5 mol %).

ⁱBoc deprotection with TFA at rt for 1 h.

^j 2o (2.5 equiv), and no K₂CO₃ was utilized.

^kUtilizing α-branched allyl ester as precursor.

^lUtilizing (E)-linear allyl esters as precursors.

^mUtilizing (Z)-linear allyl esters as precursor.