Table 5. Comparison of photocatalytic performance of Nb:W co-doped SnO2 electrodes vs. that of other TCO-based photoelectrodes.
| Sl. No. | Photoelectrode – parameters | aDye for degradation | Pollutant volume/catalyst area/light source | Performance highlights (resources) |
|---|---|---|---|---|
| 1 | TiO2 – varying calcination temperature | Degradation of MO | 25 ml/80 cm2/15 W UV lamp | TiO2 film calcined at 700 °C showed the highest rate constant of 0.0018 min−1 (ref. 8) |
| 2 | TiO2 – Sn ion implantation | Degradation of Rh B | 5 ml/5 cm2/8 W UV lamp | Rh B was degraded up to 80% after 160 min (ref. 9) |
| 3 | TiO2 – thickness variation | Degradation of SA | 100 μL/4 cm2/UV-A lamp | TiO2 film of thickness 190 nm showed the highest activity with a rate constant 0.01648 min−1 (ref. 10) |
| 4 | Al/TiO2 – thermal deposition of the Al layer | Rh B | 1.5 cm2/sunlight | An abatement of 30% was obtained for the degradation of Rh B11 |
| 5 | TiO2–ZnO – Ag doping | Degradation of MB | 2 ml/1 cm2/15 W UV lamp | 2 mol% Ag-doped TiO2 – ZnO films showed an efficiency of 80% with a rate constant of 0.758 h−1 (ref. 12) |
| 6 | ZnO – Cu doping | Degradation of orange II | Visible light | Pure ZnO film showed 72% degradation efficiency and it decreased with increasing Cu doping13 |
| 7 | ZnO – multilayer film (ZnO/AZO/ZnO) with Al doping | Degradation of MB | 40 ml/24 cm2/750 W | Maximum efficiency of 95.2% with a rate of 1.02 h−1 was obtained at 20% Al doping14 |
| 8 | ZnO – Al doping | Degradation of MB | 50 ml/1 cm2/15 W UV lamp | Al doped ZnO films showed an efficiency of 80% with a rate constant of 0.002 min−1 (ref. 15) |
| 9 | ZnO – Co doping | Degradation of MB | 50 ml/1 cm2/100 W | 15 wt% Co doped ZnO film showed 100% degradation with a rate constant of 0.013 min−1 (ref. 16) |
| 10 | SnO2 – Fe, Ni doping | Degradation of MB | 15 ml/11 W UV lamp | ∼85% efficiency was obtained for the Fe and Ni doped SnO2 with a rate constant of 0.004 min−1 (ref. 17) |
| 11 | ZnO and SnO2 – substrate modification (polytherimide and glass) | Degradation of CV | 50 ml/2 cm2/100 W UV lamp | ZnO and SnO2 films (with a polytherimide substrate) showed an efficiency of 80 and 85% with a rate constant of 0.009 and 0.006 min−1 (ref. 18) |
| 12 | SnO2 – F doping | Degradation of CV | 50 ml/2 cm2/100 W UV-lamp | Degradation efficiency increases to 96% and 92% for pure and F: SnO2 on adding H2O2 respectively19 |
| 13 | SnO2 – Ce doping | Degradation of MB | 20 ml/3.75 cm2/UV lamp | Degradation of 19.10% is obtained for 2 wt% Ce:SnO2 (ref. 20) |
| 14 | SnO2 – Sr doping | Degradation of MB | 20 ml/15 W UV lamp | Degradation efficiency of 38% was achieved for an 8 wt% Sr doped SnO2 film with a rate constant of 0.005 min−1 (ref. 21) |
| 15 | SnO2 – Nb, W doping | Degradation of (MV + MG + MB) MD | 6 ml/4 cm2/200 W LED light | Significant degradation efficiency (73%:methyl violet, 79.1%:malachite green, and 83%:methylene blue) is achieved within 120 min (present work) |
Methylene Blue – MB, Rhodamine B – Rh B, Methyl Orange – MO, Stearic Acid – SA, and Crystal Violet – CV.