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. 2025 Jun 3;7(13):4169–4182. doi: 10.1039/d5na00268k

Table 5. Comparison of photocatalytic performance of Nb:W co-doped SnO2 electrodes vs. that of other TCO-based photoelectrodes.

Sl. No. Photoelectrode – parameters aDye for degradation Pollutant volume/catalyst area/light source Performance highlights (resources)
1 TiO2 – varying calcination temperature Degradation of MO 25 ml/80 cm2/15 W UV lamp TiO2 film calcined at 700 °C showed the highest rate constant of 0.0018 min−1 (ref. 8)
2 TiO2 – Sn ion implantation Degradation of Rh B 5 ml/5 cm2/8 W UV lamp Rh B was degraded up to 80% after 160 min (ref. 9)
3 TiO2 – thickness variation Degradation of SA 100 μL/4 cm2/UV-A lamp TiO2 film of thickness 190 nm showed the highest activity with a rate constant 0.01648 min−1 (ref. 10)
4 Al/TiO2 – thermal deposition of the Al layer Rh B 1.5 cm2/sunlight An abatement of 30% was obtained for the degradation of Rh B11
5 TiO2–ZnO – Ag doping Degradation of MB 2 ml/1 cm2/15 W UV lamp 2 mol% Ag-doped TiO2 – ZnO films showed an efficiency of 80% with a rate constant of 0.758 h−1 (ref. 12)
6 ZnO – Cu doping Degradation of orange II Visible light Pure ZnO film showed 72% degradation efficiency and it decreased with increasing Cu doping13
7 ZnO – multilayer film (ZnO/AZO/ZnO) with Al doping Degradation of MB 40 ml/24 cm2/750 W Maximum efficiency of 95.2% with a rate of 1.02 h−1 was obtained at 20% Al doping14
8 ZnO – Al doping Degradation of MB 50 ml/1 cm2/15 W UV lamp Al doped ZnO films showed an efficiency of 80% with a rate constant of 0.002 min−1 (ref. 15)
9 ZnO – Co doping Degradation of MB 50 ml/1 cm2/100 W 15 wt% Co doped ZnO film showed 100% degradation with a rate constant of 0.013 min−1 (ref. 16)
10 SnO2 – Fe, Ni doping Degradation of MB 15 ml/11 W UV lamp ∼85% efficiency was obtained for the Fe and Ni doped SnO2 with a rate constant of 0.004 min−1 (ref. 17)
11 ZnO and SnO2 – substrate modification (polytherimide and glass) Degradation of CV 50 ml/2 cm2/100 W UV lamp ZnO and SnO2 films (with a polytherimide substrate) showed an efficiency of 80 and 85% with a rate constant of 0.009 and 0.006 min−1 (ref. 18)
12 SnO2 – F doping Degradation of CV 50 ml/2 cm2/100 W UV-lamp Degradation efficiency increases to 96% and 92% for pure and F: SnO2 on adding H2O2 respectively19
13 SnO2 – Ce doping Degradation of MB 20 ml/3.75 cm2/UV lamp Degradation of 19.10% is obtained for 2 wt% Ce:SnO2 (ref. 20)
14 SnO2 – Sr doping Degradation of MB 20 ml/15 W UV lamp Degradation efficiency of 38% was achieved for an 8 wt% Sr doped SnO2 film with a rate constant of 0.005 min−1 (ref. 21)
15 SnO2 – Nb, W doping Degradation of (MV + MG + MB) MD 6 ml/4 cm2/200 W LED light Significant degradation efficiency (73%:methyl violet, 79.1%:malachite green, and 83%:methylene blue) is achieved within 120 min (present work)
a

Methylene Blue – MB, Rhodamine B – Rh B, Methyl Orange – MO, Stearic Acid – SA, and Crystal Violet – CV.