2. Molar Metal Ratio and Tin Loading on Catalyst Surface Measured by SEM-EDX and XPS.
| fresh
catalyst |
used
catalyst |
|||
|---|---|---|---|---|
| desired catalyst | EDX (Ru/Sn) | surface tin-loading (XPS) | EDX (Ru/Sn) | surface tin content (XPS) |
| Ru1Sn1/C | 1:0.54 | 0.14 | 1:0.57 | 0.05 |
| Ru1Sn2.3/C | 1:0.81 | 0.23 | 1:0.82 | 0.08 |
| Ru1Sn4/C | 1:1.24 | 0.26 | 0.16 | |
No tin and ruthenium left on the catalyst as proven by XPS.