| Crystal data |
| Chemical formula |
C19H19NO4
|
C15H13NO2
|
|
M
r
|
325.35 |
239.26 |
| Crystal system, space group |
Orthorhombic, P212121
|
Orthorhombic, Pca21
|
| Temperature (K) |
100 |
100 |
|
a, b, c (Å) |
4.8393 (2), 12.4928 (4), 27.3101 (9) |
15.3560 (3), 5.0400 (1), 31.0254 (7) |
|
V (Å3) |
1651.07 (10) |
2401.19 (9) |
|
Z
|
4 |
8 |
| Radiation type |
Cu Kα |
Cu Kα |
| μ (mm−1) |
0.75 |
0.71 |
| Crystal size (mm) |
0.3 × 0.03 × 0.01 |
0.25 × 0.03 × 0.01 |
| |
| Data collection |
| Diffractometer |
Bruker D8 Venture Photon III |
Bruker D8 Venture Photon III |
| Absorption correction |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
Multi-scan (SADABS; Krause et al., 2015 ▸) |
|
Tmin, Tmax
|
0.664, 0.753 |
0.683, 0.753 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
25780, 2922, 2590 |
18874, 4069, 3754 |
|
R
int
|
0.081 |
0.051 |
| (sin θ/λ)max (Å−1) |
0.596 |
0.596 |
| |
| Refinement |
|
R[F2 > 2σ(F2)], wR(F2), S
|
0.032, 0.073, 1.06 |
0.030, 0.068, 1.05 |
| No. of reflections |
2922 |
4069 |
| No. of parameters |
226 |
341 |
| No. of restraints |
0 |
1 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
0.12, −0.17 |
0.14, −0.17 |
| Absolute structure |
Flack x determined using 992 quotients [(I+)−(I−)]/[(I+)+(I−)] (Parsons et al., 2013 ▸) |
Flack x determined using 1617 quotients [(I+)−(I−)]/[(I+)+(I−)] (Parsons et al., 2013 ▸) |
| Absolute structure parameter |
−0.05 (14) |
−0.26 (13) |
