2. Translation Self-Diffusion Coefficients and Hydrodynamic Volumes of 1, 1 D , 2, and 2 D Measured by PGSE NMR in Various Solvents.
| entry | catalyst | solvent | Dt (×10–10 m2 s–1) | VH (Å3) |
|---|---|---|---|---|
| 1 | 1 D | D2O | 3.54 | 864 ± 130 |
| 2 | 2 D | D2O | 3.50 | 847 ± 127 |
| 3 | 1 | D2O | 4.42 | 505 ± 76 |
| 4 | 1 D | DMSO-d6 | 0.17 | 1052 ± 158 |
| 5 | 2 D | DMSO-d6 | 0.20 | 767 ± 106 |
| 6 | 1 | CD3CN | 1.45 | 572 ± 86 |
| 7 | 2 | CD3CN | 1.41 | 613 ± 92 |
| 8 | 1 D | CD3CN | 1.06 | 1232 ± 185 |
| 9 | 2 D | CD3CN | 1.12 | 1098 ± 165 |
a
Obtained upon dissolution of 1 and 2 in D2O.
b
Obtained upon addition of KCl to a solution of 1 D in D2O.