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. 2025 May 19;15(11):9417–9429. doi: 10.1021/acscatal.5c02162

4. Comparison of the Kinetic Constants Obtained by the Fitting of the Experimental Data of Catalyst 1 with Literature Values .

  k2 (M–1 s–1) k3 (M–1 s–1) KM (M–1)
1 23 ± 5 1889 ± 154 150 ± 62
[Cp*Ir(6-NH2-pysa)NO3] 6.40 ± 0.83 970 ± 40 191 ± 44
a

Reaction conditions: [cat] = 7.5 μM; [H2PO3 –/HPO3 2–] = 0.4 M; pH = 6.58; T = 313 K for 1 and [cat] = 5.0 μM; [H2PO3 –/HPO3 2–] = 0.4 M; pH = 6.58; T = 313 K for [Cp*Ir­(6-NH2-pysa)­NO3].