5. TOF Values and Reaction Conditions of Some Catalysts for the Regeneration of NADH.
| catalyst | [cat] (μM) | [NAD+] (mM) | [DH–] (M) | pH | T (°C) | TOF (h–1) |
|---|---|---|---|---|---|---|
| [Cp*Rh(phen)Cl]+ , | 25 | 0.4 | 0.5 | 7 | 38 | 81.5 |
| [Cp*Rh(phen)Cl]+ | 8 | 8 | 0.35 | 7 | 60 | 2000 |
| [Cp*Ir(5-NO2phen)Cl]+ | 80 | 8 | 0.35 | 7 | 38 | 58 |
| [Cp*Ir(6-NH2pysa)NO3] | 5 | 3 | 0.4 | 6.58 | 40 | 3731 |
| [Cp*Ir(pysaNphCOOH)Cl] | 8 | 8 | 0.35 | 6.5 | 37 | 1436 |
| [Cp*Ir(pica)Cl] | 7.5 | 0.77 | 0.125 | 7 | 25 | 143 |
| [Cp*Ir(picaNphCOOH)Cl] | 0.8 | 8 | 0.35 | 6.5 | 37 | 7825 |
| 1 | 7.5 | 6 | 0.4 | 6.58 | 40 | 13090 |
a
Formate (HCOO–) in phosphate buffer.
b
Phosphite buffer (H2PO3 –/HPO3 2–).