1. (Co)­polymerization of Propylene (and 11-Bromo-1-undecene) .

entry	[11-Br] (mM)	activity	productivity	yield (g)	incorporation (mol %)	Mw (kg mol–1)	D̵ M
1‴	0	10,100	32.1	8.03	0.00	98	4.7
2‴	91	3580	11.4	4.27	2.96	226	2.8
2‴	137	2090	6.65	2.49	4.78	172	2.7
2‴	182	1230	3.92	1.47	9.10	163	2.5

^aConditions: dimethylsilylene bis­(2-methyl-4-phenyl-1-indenyl) zirconium dichloride (Zr), MAO used as a cocatalyst and scavenger with [Al]₀:[Zr]₀ = 1000:1. Molar ratio of [TIBA]₀:[11-Br]₀ = 1:10, 0.5 mL toluene, 49.5 mL hexanes, propylene 2 bar, polymerization temperature = 50 °C, 0.5 h. Polymerization was performed at least in duplicate and mean values reported.

^bkg_PP mol_Zr ^–1 h^–1 bar^–1.

^ckgPP g_Zr ^–1 h^–1.

^dDetermined by ¹H NMR spectroscopy.

^eDetermined by SEC using the Mark–Houwink correction for PP.