1. NMR Data of Compounds 1–6 (δ in ppm).

	1		2		3		4		5		6
no.	δC	δH mult. (J in Hz)	δC	δH mult. (J in Hz)	δC	δH mult. (J in Hz)	δC	δH mult. (J in Hz)	δC	δH mult. (J in Hz)	δC	δH mult. (J in Hz)
1	35.7	2.91 m	35.9	2.92 m	34.7	2.89 m	33.8	2.83 m	34.9	2.99 m	34.3	2.86 m
		1.55 m		1.86 m		1.51 m		1.72 m		1.85 m		1.79 m
2	34.7	2.58 m	34.5	2.65 m	34.5	2.59 m	34.2	2.69 m	34.5	2.71 m	37.5	2.62 m
		2.42 m		2.42 m		2.47 m		2.48 m		2.42 m		2.49 m
3	220.3		220.6		219.1		218.1		218.4		217.6
4	50.2		50.1		50.4		50.3		50.0		53.4
5	49.3	1.80 dd (14.0, 1.9)	48.9	1.94 dd (13.9, 2.0)	49.3	1.81 dd (14.2, 1.9)	51.6	2.45 dd (14.1, 1.9)	49.8	2.42 dd (15.2, 3.1)	45.2	2.89 dd (12.9, 2.4)
6	27.0	2.18 m	27.1	2.13 m	27.2	2.24 m	36.9	2.57 m	36.4	2.60 m	37.9	2.77 m
		1.56 m		1.53 m		1.66 m		2.72 dd (14.1, 8.9)		2.55 dd (14.8, 3.1)		2.38 dd (13.1, 2.4)
7	66.3	4.83 dd (9.6, 7.5)	66.2	4.84 dd (9.4, 7.7)	65.9	4.94 dd (9.4, 7.7)	198.2	4.83 dd (9.6, 7.5)	204.1		201.6
8	158.0		160.8		161.3		147.6		151.1		148.1
9	140.8		138.8		142.2		148.6		152.5		151.5
10	38.0		38.1		37.9		38.9		38.9		40.5
11	197.8		201.1		189.3		201.9		201.3		201.3
12	50.3	2.75 s	78.9	3.82 s	197.6		77.9	4.52 s	52.0	2.81 d (16.8)	50.0	3.10 d (15.9)
										2.59 d (16.8)		2.76 d (15.9)
13	45.0		46.7		61.8		49.4		47.7		45.1
14	59.4		58.7		61.9		58.0		52.8		58.7
15	218.1		218.4		215.2		206.5		72.3	4.28 dd (9.2, 6.1)	210.4
16	41.4	2.75 dd (19.4, 8.1)	41.5	2.79 dd (19.4, 8.6)	41.2	2.85 dd (19.8, 8.6)	37.5	2.72 dd (18.3, 8.3)	36.4	2.58 m	41.0	2.91 dd (18.3, 9.7)
		2.08 dd (19.4, 9.7)		2.11 dd (19.4, 9.8)		2.15 dd (19.8, 10.0)		2.01 dd (18.3, 8.1)		1.92 m		1.87 dd (18.3, 8.1)
17	46.4	1.99 m	39.2	2.69 m	39.6	2.66 m	45.8	2.59 m	48.4	1.82 m	46.1	2.28 m
18	18.0	1.00 s	18.5	0.98 s	14.2	1.29 s	10.9	0.66 s	17.6	0.86 s	16.4	0.89 s
19	19.3	1.21 s	19.9	1.12 s	18.8	1.33 s	19.5	1.38 s	18.2	1.27 s	18.8	1.34 s
20	35.7	2.01 m	35.9	1.58 m	36.3	1.46 m	33.0	1.70 m	36.0	1.39 m	36.9	1.58 m
21	18.3	1.02 d (6.5)	17.2	1.11 d (6.5)	18.3	1.01 d (6.5)	20.4	1.16 d (6.5)	18.6	0.89 d (6.5)	18.9	1.05 d (6.5)
22	34.6	1.65 m	34.6	1.53 m	34.3	1.51 m	34.0	1.54 m	34.5	1.55 m	35.6	1.55 m
		1.45 m		1.21 m		1.34 m		1.18 m		1.21 m		1.29 m
23	25.8	2.28 m	25.9	2.31 m	26.1	2.33 m	26.7	2.28 m	25.8	2.34 m	26.4	2.32 m
		2.15 m		2.16 m		2.16 m		2.15 m		2.11 m		2.20 m
24	144.2	6.84 t (7.3)	144.7	6.87 t (7.3)	144.2	6.84 t (7.3)	144.6	6.85 t (7.3)	144.7	6.85 t (7.3)	143.8	6.79 t (7.3)
25	127.5		127.3		127.5		127.2		127.3		129.1
26	172.1		172.1		171.5		172.0		172.4		171.6
27	12.3	1.85 s	12.3	1.86 s	12.3	1.86 s	12.2	1.83 s	12.2	1.83 s	12.4	1.84 s
28	22.2	1.33 s	22.3	1.34 s	22.2	1.32 s	22.7	1.31 s	22.7	1.31 s	17.2	1.01 s
29	65.7	4.08 d (11.3)	65.6	4.07 d (11.3)	65.5	4.05 d (11.3)	65.5	3.99 d (11.3)	65.4	3.98 d (11.3)	68.5	3.50 d (10.8)
		3.44 d (11.3)		3.44 d (11.3)		3.49 d (11.3)		3.47 d (11.3)		3.47 d (11.3)		3.39 d (10.8)
30	24.9	1.34 s	27.1	1.35 s	27.5	1.27 s	20.1	1.75 s	20.6	1.19 s	21.1	1.70 s

^{a 1}H NMR (500 MHz) and ¹³C NMR (125 MHz) spectral data were measured in CDCl₃.

^{b 1}H NMR (500 MHz) and ¹³C NMR (125 MHz) spectral data were measured in CD₃OD.