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. 2025 Jun 20;15:20175. doi: 10.1038/s41598-025-05836-x

Table 3.

Impedance parameters for CS in 4 M HCl free and containing various concentrations of the prepared inhibitors at room temperature.

Inh Conc. M RS (Ω.cm2) CPE Rct (Ω.cm2) Rf (Ω.cm2) RP (Ω.cm2) Cdl, (F/cm2) × 10–9 τ, (s) χ2 × 10–3 Inline graphic
n Y° (μF)
Blank 2.386 ± 1.02 0.8532 ± 0.07 418.18 ± 1.45 35.24 ± 3.13 35.24 ± 1.15 65.81 0.0134 4.013
DCSM-8 1 × 10–6 2.707 ± 0.91 0.8525 ± 0.08 62.29 ± 1.27 545.53 ± 2.05 8.24 ± 0.15 553.77 ± 1.06 9.75 0.030 3.241 93.64
1 × 10–5 4.488 ± 0.80 0.8488 ± 0.07 22.57 ± 1.35 628.64 ± 3.14 9.31 ± 0.09 637.95 ± 1.33 8.46 0.038 2.847 94.48
5 × 10–5 5.419 ± 0.72 0.8379 ± 0.03 17.33 ± 2.02 704.24 ± 3.42 12.52 ± 0.08 716.76 ± 2.20 6.28 0.050 2.771 95.08
1 × 10–4 6.230 ± 1.13 0.8303 ± 0.09 13.53 ± 1.93 832.3 ± 4.06 16.33 ± 0.08 848.63 ± 1.13 3.62 0.058 1.984 95.85
5 × 10–4 6.809 ± 0.92 0.8232 ± 0.08 11.39 ± 2.28 891.47 ± 2.65 19.84 ± 0.14 911.31 ± 3.05 3.04 0.064 0.859 96.13
1 × 10–3 7.687 ± 0.85 0.8095 ± 0.06 8.25 ± 3.30 982.88 ± 4.12 21.27 ± 0.17 1004.15 ± 2.17 1.63 0.072 1.221 96.49
DCSM-10 1 × 10–6 4.702 ± 1.14 0.8265 ± 0.12 49.48 ± 2.15 593.32 ± 1.55 9.11 ± 0.07 602.43 ± 2.21 7.57 0.071 2.230 94.15
1 × 10–5 4.915 ± 0.76 0.8367 ± 0.08 18.24 ± 2.34 684.48 ± 1.96 11.34 ± 0.14 695.82 ± 2.50 7.02 0.083 2.182 94.94
5 × 10–5 5.296 ± 0.90 0.8452 ± 0.16 16.08 ± 1.86 768.54 ± 2.77 17.02 ± 0.09 785.56 ± 1.37 6.11 0.088 1.873 95.51
1 × 10–4 4.805 ± 1.04 0.8388 ± 0.09 10.43 ± 3.10 872.42 ± 1.69 20.16 ± 0.19 892.58 ± 2.26 3.06 0.091 1.624 96.05
5 × 10–4 4.937 ± 0.82 0.8456 ± 0.09 8.86 ± 1.79 963.72 ± 2.60 24.41 ± 0.16 988.13 ± 3.09 2.24 0.094 0.937 96.43
1 × 10–3 5.602 ± 0.68 0.8456 ± 0.08 7.10 ± 2.46 1087.59 ± 3.15 28.97 ± 0.08 1116.56 ± 1.14 1.41 0.103 0.881 96.84
DCSM-12 1 × 10–6 4.209 ± 0.87 0.8234 ± 0.06 21.17 ± 3.06 676.75 ± 2.51 10.28 ± 0.07 687.03 ± 3.05 4.42 0.166 2.024 94.87
1 × 10–5 5.413 ± 0.96 0.8345 ± 0.03 13.69 ± 3.44 788.73 ± 3.20 13.32 ± 0.13 802.05 ± 3.36 3.65 0.193 1.883 95.61
5 × 10–5 4.722 ± 1.08 0.8133 ± 0.08 11.11 ± 2.71 894.53 ± 2.07 19.21 ± 0.08 913.74 ± 2.32 3.21 0.215 1.540 96.14
1 × 10–4 4.226 ± 0.95 0.8345 ± 0.07 9.58 ± 2.32 1018.73 ± 4.11 23.25 ± 0.08 1041.98 ± 2.27 2.81 0.266 0.802 96.62
5 × 10–4 7.287 ± 1.21 0.8187 ± 0.11 8.04 ± 1.52 1108.53 ± 3.21 27.08 ± 0.12 1135.61 ± 1.56 1.46 0.293 0.626 96.90
1 × 10–3 7.578 ± 0.86 0.8096 ± 0.09 6.78 ± 1.77 1214.17 ± 2.33 31.37 ± 0.11 1245.54 ± 1.72 0.35 0.303 0.792 97.17