Table 3.
Impedance parameters for CS in 4 M HCl free and containing various concentrations of the prepared inhibitors at room temperature.
| Inh | Conc. M | RS (Ω.cm2) | CPE | Rct (Ω.cm2) | Rf (Ω.cm2) | RP (Ω.cm2) | Cdl, (F/cm2) × 10–9 | τ, (s) | χ2 × 10–3 | ![]() |
|
|---|---|---|---|---|---|---|---|---|---|---|---|
| n | Y° (μF) | ||||||||||
| – | Blank | 2.386 ± 1.02 | 0.8532 ± 0.07 | 418.18 ± 1.45 | 35.24 ± 3.13 | – | 35.24 ± 1.15 | 65.81 | 0.0134 | 4.013 | – |
| DCSM-8 | 1 × 10–6 | 2.707 ± 0.91 | 0.8525 ± 0.08 | 62.29 ± 1.27 | 545.53 ± 2.05 | 8.24 ± 0.15 | 553.77 ± 1.06 | 9.75 | 0.030 | 3.241 | 93.64 |
| 1 × 10–5 | 4.488 ± 0.80 | 0.8488 ± 0.07 | 22.57 ± 1.35 | 628.64 ± 3.14 | 9.31 ± 0.09 | 637.95 ± 1.33 | 8.46 | 0.038 | 2.847 | 94.48 | |
| 5 × 10–5 | 5.419 ± 0.72 | 0.8379 ± 0.03 | 17.33 ± 2.02 | 704.24 ± 3.42 | 12.52 ± 0.08 | 716.76 ± 2.20 | 6.28 | 0.050 | 2.771 | 95.08 | |
| 1 × 10–4 | 6.230 ± 1.13 | 0.8303 ± 0.09 | 13.53 ± 1.93 | 832.3 ± 4.06 | 16.33 ± 0.08 | 848.63 ± 1.13 | 3.62 | 0.058 | 1.984 | 95.85 | |
| 5 × 10–4 | 6.809 ± 0.92 | 0.8232 ± 0.08 | 11.39 ± 2.28 | 891.47 ± 2.65 | 19.84 ± 0.14 | 911.31 ± 3.05 | 3.04 | 0.064 | 0.859 | 96.13 | |
| 1 × 10–3 | 7.687 ± 0.85 | 0.8095 ± 0.06 | 8.25 ± 3.30 | 982.88 ± 4.12 | 21.27 ± 0.17 | 1004.15 ± 2.17 | 1.63 | 0.072 | 1.221 | 96.49 | |
| DCSM-10 | 1 × 10–6 | 4.702 ± 1.14 | 0.8265 ± 0.12 | 49.48 ± 2.15 | 593.32 ± 1.55 | 9.11 ± 0.07 | 602.43 ± 2.21 | 7.57 | 0.071 | 2.230 | 94.15 |
| 1 × 10–5 | 4.915 ± 0.76 | 0.8367 ± 0.08 | 18.24 ± 2.34 | 684.48 ± 1.96 | 11.34 ± 0.14 | 695.82 ± 2.50 | 7.02 | 0.083 | 2.182 | 94.94 | |
| 5 × 10–5 | 5.296 ± 0.90 | 0.8452 ± 0.16 | 16.08 ± 1.86 | 768.54 ± 2.77 | 17.02 ± 0.09 | 785.56 ± 1.37 | 6.11 | 0.088 | 1.873 | 95.51 | |
| 1 × 10–4 | 4.805 ± 1.04 | 0.8388 ± 0.09 | 10.43 ± 3.10 | 872.42 ± 1.69 | 20.16 ± 0.19 | 892.58 ± 2.26 | 3.06 | 0.091 | 1.624 | 96.05 | |
| 5 × 10–4 | 4.937 ± 0.82 | 0.8456 ± 0.09 | 8.86 ± 1.79 | 963.72 ± 2.60 | 24.41 ± 0.16 | 988.13 ± 3.09 | 2.24 | 0.094 | 0.937 | 96.43 | |
| 1 × 10–3 | 5.602 ± 0.68 | 0.8456 ± 0.08 | 7.10 ± 2.46 | 1087.59 ± 3.15 | 28.97 ± 0.08 | 1116.56 ± 1.14 | 1.41 | 0.103 | 0.881 | 96.84 | |
| DCSM-12 | 1 × 10–6 | 4.209 ± 0.87 | 0.8234 ± 0.06 | 21.17 ± 3.06 | 676.75 ± 2.51 | 10.28 ± 0.07 | 687.03 ± 3.05 | 4.42 | 0.166 | 2.024 | 94.87 |
| 1 × 10–5 | 5.413 ± 0.96 | 0.8345 ± 0.03 | 13.69 ± 3.44 | 788.73 ± 3.20 | 13.32 ± 0.13 | 802.05 ± 3.36 | 3.65 | 0.193 | 1.883 | 95.61 | |
| 5 × 10–5 | 4.722 ± 1.08 | 0.8133 ± 0.08 | 11.11 ± 2.71 | 894.53 ± 2.07 | 19.21 ± 0.08 | 913.74 ± 2.32 | 3.21 | 0.215 | 1.540 | 96.14 | |
| 1 × 10–4 | 4.226 ± 0.95 | 0.8345 ± 0.07 | 9.58 ± 2.32 | 1018.73 ± 4.11 | 23.25 ± 0.08 | 1041.98 ± 2.27 | 2.81 | 0.266 | 0.802 | 96.62 | |
| 5 × 10–4 | 7.287 ± 1.21 | 0.8187 ± 0.11 | 8.04 ± 1.52 | 1108.53 ± 3.21 | 27.08 ± 0.12 | 1135.61 ± 1.56 | 1.46 | 0.293 | 0.626 | 96.90 | |
| 1 × 10–3 | 7.578 ± 0.86 | 0.8096 ± 0.09 | 6.78 ± 1.77 | 1214.17 ± 2.33 | 31.37 ± 0.11 | 1245.54 ± 1.72 | 0.35 | 0.303 | 0.792 | 97.17 | |
