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Activation thermodynamic parameters of CS in 4 M HCl free and containing DCSM-8, DCSM-10, and DCSM-12 at several temperatures.
| Inh | Arrhenius | Transition state | ||
|---|---|---|---|---|
| Ea, (kJ.mol-1) | R2 | ΔH*, (kJ.mol-1) | ΔS*, (J.mol-1) | |
| Blank | 30.335 | 0.9898 | 27.738 | -142.498 |
| DCSM-8 | 36.498 | 0.9939 | 29.802 | -149.962 |
| DCSM-10 | 33.733 | 0.9941 | 31.136 | -154.199 |
| DCSM-12 | 32.397 | 0.9937 | 33.901 | -159.241 |
