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The layer substructure of compound 3, which involves the two tetrachloridoaurate ions at Au1 and Au2 together with the free chloride Cl9, viewed parallel to the b axis in the region y ≃ 0.5. Dashed interactions indicate Cl⋯Cl and Au⋯Cl contacts. Contacts Au1⋯Cl6 (−1 + x, y, z) of 4.0588 (9) Å were considered too long for inclusion.
