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. 2025 Jun 24;7(16):5019–5030. doi: 10.1039/d5na00266d

Table 2. Adsorption results like adsorption energies (Ead), distances (d), work functions (Φ), work function changes (ΔΦ) and recovery times (τ) for SO2, SO2F2 and SOF4 molecules on the Ir modified BP/BSe heterostructures.

Structure E ad (eV) d (Å) Φ (eV) Δφ (eV) τ (s)
Ir-BP-BSe@H2S −0.68 2.33 (Ir–S) 5.00 −0.25 0.32
Ir-BP-BSe@SO2F2(i) −2.97 1.98 (Ir–F) 6.25 1.00 1.60 × 1038
Ir-BP-BSe@SO2F2(ii) −0.45 2.78 (Ir–S) 5.21 −0.04 4.06 × 10−5
Ir-BP-BSe@SOF4(i) −2.55 2.07 (Ir–O) 5.63 0.38 1.33 × 1031
Ir-BP-BSe@SOF4(ii) −2.62 2.16 (Ir–O), 2.31 (Ir–S) 5.92 0.67 1.98 × 1032