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. 2025 Jun 25;125(14):6609–6652. doi: 10.1021/acs.chemrev.4c01014

1. Wigner Threshold Laws for Universal Scalings of Collision Cross Sections σ­(k) as a Function of the Wavenumber k for Two-Body Collisions in Three Dimensions .

  Inelastic
 
lim r→∞ V(r) Endothermic Exothermic Depolarization Elastic
0 k2l+1 k2l1 k2l+2l k4l
Ze2/r exp(−2πμZe 2/(ℏ2 k)) k–2 exp(−2πμZe 2/(ℏ2 k)) k–2 exp(−4πμZe 2/(ℏ2 k)) k –2
Ze 2/r 1 k –2 k –2 k –2
a

Scalings are shown for elastic collisions and inelastic collisions with positive threshold energy (endothermic reactions), negative threshold energy (exothermic reactions), and changes in angular momentum (depolarization events) and are given for short-range (lim r→∞ V(r)) and long-range (attractive Coulombic lim r→∞ V(r) = −Ze 2/r and repulsive Coulombic lim r→∞ V(r) = −Ze 2/r) potentials. Expressions are provided in terms of the reduced mass μ, charge number product Z, and initial l and final angular momentum l quantum numbers of the collision partners, where e is the electron charge and is reduced Planck’s constant.